Results 21 to 30 of about 142,191 (132)
LnRu‐3 dimeric LnIII/GaIII metallacrows bearing four RuII chromophoric complexes have been synthesized and proved to exhibit characteristic emissions of YbIII, NdIII and ErIII in the NIR‐II region upon excitation with visible light through metal‐to‐ligand charge transfer (MLCT) states.
Codruţa C. Bădescu‐Singureanu +4 more
wiley +2 more sources
The Versatility of Diazirines: Properties, Synthetic and Modern Applications
Diazirines are 3‐membered heterocycles containing two nitrogen atoms connected by a double bond. They possess a multi‐faceted reactivity that holds great potential for organic synthesis. This review discusses their properties, modes of activation, and their many modern uses, underlining their underappreciated versatility: as carbene precursors, but ...
Mathieu L. Lepage, Emmanuel Gras
wiley +1 more source
This study explores how changing halidesfrom Cl to Iinfluences ionic radius, antioxidant activity, and lipophilicity. These shifts significantly impact the biological potency of [Cu(IPr)X] compounds against Leishmania parasites and arboviruses. A strategic tweak in halogen identity paves the way for enhanced therapeutic performance in metal‐based drug ...
J. V. Fontes +9 more
wiley +1 more source
Recently, a number of organisations have called for open access to scientific information and especially to the data obtained from publicly funded research, among which the Royal Society report and the European Commission press release are particularly ...
C. Bird, J. Frey
semanticscholar +1 more source
Abstract The aim of this work is to provide a model‐backed hypothesis for the formation of evaporites—sulfates, borates—in Gale crater using thermochemical modeling to determine constraints on their formation. We test the hypothesis that primary evaporites required multiple wet–dry cycles to form, akin to how evaporite assemblages form on Earth ...
D. Das +12 more
wiley +1 more source
Eduardo Lissi, Dorita Adamo‐Lissi and Juan Grotewold in Aberystwyth, Wales, winter 1961. Upon their return to Buenos Aires in 1963, with their PhD degrees, Lissi and Grotewold started a Chemical Kinetics and Photochemistry group in the School of Sciences (University of Buenos Aires).
Silvia E. Braslavsky +1 more
wiley +1 more source
Shade houses serve as effective scientific tools for ex situ cultivation and orchid conservation in tropical forests. A comparison of the floral scent chemistry of Cyrtorchis letouzeyi between shade houses and natural populations in Cameroon revealed the same dominant compound, identical qualitative compositions across sites, but variations in emission
Kamga Lydie Messado +4 more
wiley +1 more source
Recent Advances in Biosensors Based on Hybridization Chain Reaction and Silver Nanoclusters
This review explores the integration of hybridization chain reaction (HCR) with silver nanoclusters (AgNCs) to form hybrid HCR‐AgNCs biosensors, highlighting advancements in their design, performance, and practical applications. It covers recent innovations, methodological improvements, and the potential of HCR‐AgNCs systems as detectors across various
Zheng Wei Wong, Siu Yee New
wiley +1 more source
Formation of Structurally Bound Carbonate in Silicate Melts on the Top of the Mantle Transition Zone
Abstract Carbon‐bearing dense silicate melts may account for the seismically weak layers on top of the mantle transition zone (MTZ) at 13–14 GPa. How carbon is incorporated into silicate melts at such high pressures has not been experimentally probed, making the nature of carbon in dense melts elusive.
Eun Jeong Kim, Sung Keun Lee
wiley +1 more source
A detailed comparison of σ‐donation indicators, including the calculated 1JC−H coupling constant, across a broad spectrum of diverse carbenes provides new insights into their strengths and limitations. This study highlights the utility of 1JC−H for assessing σ‐donation in structurally similar carbenes, while revealing its constraints for carbenes with ...
Radhika Gupta, Gilles Frison
wiley +1 more source

