Results 21 to 30 of about 142,191 (132)

Enabling Visible Light Sensitization of YbIII, NdIII and ErIII in Dimeric LnIII/GaIII Metallacrowns through Functionalization with RuII Complexes for NIR‐II Multiplex Imaging

open access: yesAngewandte Chemie, Volume 137, Issue 3, January 15, 2025.
LnRu‐3 dimeric LnIII/GaIII metallacrows bearing four RuII chromophoric complexes have been synthesized and proved to exhibit characteristic emissions of YbIII, NdIII and ErIII in the NIR‐II region upon excitation with visible light through metal‐to‐ligand charge transfer (MLCT) states.
Codruţa C. Bădescu‐Singureanu   +4 more
wiley   +2 more sources

The Versatility of Diazirines: Properties, Synthetic and Modern Applications

open access: yesChemistry – A European Journal, Volume 31, Issue 43, August 1, 2025.
Diazirines are 3‐membered heterocycles containing two nitrogen atoms connected by a double bond. They possess a multi‐faceted reactivity that holds great potential for organic synthesis. This review discusses their properties, modes of activation, and their many modern uses, underlining their underappreciated versatility: as carbene precursors, but ...
Mathieu L. Lepage, Emmanuel Gras
wiley   +1 more source

The Halogen Effect in [Cu(NHC)X] Compounds: A Case Study on the Anti‐Leishmania and Antiviral Activity of [Cu(IPr)X]

open access: yesChemistrySelect, Volume 10, Issue 31, August 15, 2025.
This study explores how changing halidesfrom Cl to Iinfluences ionic radius, antioxidant activity, and lipophilicity. These shifts significantly impact the biological potency of [Cu(IPr)X] compounds against Leishmania parasites and arboviruses. A strategic tweak in halogen identity paves the way for enhanced therapeutic performance in metal‐based drug ...
J. V. Fontes   +9 more
wiley   +1 more source

Chemical information matters: an e-Research perspective on information and data sharing in the chemical sciences.

open access: yesChemical Society Reviews, 2013
Recently, a number of organisations have called for open access to scientific information and especially to the data obtained from publicly funded research, among which the Royal Society report and the European Commission press release are particularly ...
C. Bird, J. Frey
semanticscholar   +1 more source

Simulating evaporative wet and dry cycles in Gale crater, Mars using thermochemical modeling techniques

open access: yesMeteoritics &Planetary Science, Volume 60, Issue 8, Page 1704-1720, August 2025.
Abstract The aim of this work is to provide a model‐backed hypothesis for the formation of evaporites—sulfates, borates—in Gale crater using thermochemical modeling to determine constraints on their formation. We test the hypothesis that primary evaporites required multiple wet–dry cycles to form, akin to how evaporite assemblages form on Earth ...
D. Das   +12 more
wiley   +1 more source

The photochemical inheritance of Eduardo Lissi and Juan Grotewold and the intersystem crossings with other inheritances

open access: yesPhotochemistry and Photobiology, Volume 101, Issue 4, Page 790-832, July/August 2025.
Eduardo Lissi, Dorita Adamo‐Lissi and Juan Grotewold in Aberystwyth, Wales, winter 1961. Upon their return to Buenos Aires in 1963, with their PhD degrees, Lissi and Grotewold started a Chemical Kinetics and Photochemistry group in the School of Sciences (University of Buenos Aires).
Silvia E. Braslavsky   +1 more
wiley   +1 more source

Floral Scent Variation in Cyrtorchis letouzeyi (Orchidaceae) Between Natural Versus Cultivated Environments

open access: yesBiotropica, Volume 57, Issue 3, May 2025.
Shade houses serve as effective scientific tools for ex situ cultivation and orchid conservation in tropical forests. A comparison of the floral scent chemistry of Cyrtorchis letouzeyi between shade houses and natural populations in Cameroon revealed the same dominant compound, identical qualitative compositions across sites, but variations in emission
Kamga Lydie Messado   +4 more
wiley   +1 more source

Recent Advances in Biosensors Based on Hybridization Chain Reaction and Silver Nanoclusters

open access: yesSmall Methods, Volume 9, Issue 4, April 22, 2025.
This review explores the integration of hybridization chain reaction (HCR) with silver nanoclusters (AgNCs) to form hybrid HCR‐AgNCs biosensors, highlighting advancements in their design, performance, and practical applications. It covers recent innovations, methodological improvements, and the potential of HCR‐AgNCs systems as detectors across various
Zheng Wei Wong, Siu Yee New
wiley   +1 more source

Formation of Structurally Bound Carbonate in Silicate Melts on the Top of the Mantle Transition Zone

open access: yesGeophysical Research Letters, Volume 52, Issue 3, 16 February 2025.
Abstract Carbon‐bearing dense silicate melts may account for the seismically weak layers on top of the mantle transition zone (MTZ) at 13–14 GPa. How carbon is incorporated into silicate melts at such high pressures has not been experimentally probed, making the nature of carbon in dense melts elusive.
Eun Jeong Kim, Sung Keun Lee
wiley   +1 more source

Correlation Between NMR Coupling Constants and σ‐Donating Properties of N‐Heterocyclic Carbenes and Their Derivatives

open access: yesChemistry – A European Journal, Volume 31, Issue 4, January 17, 2025.
A detailed comparison of σ‐donation indicators, including the calculated 1JC−H coupling constant, across a broad spectrum of diverse carbenes provides new insights into their strengths and limitations. This study highlights the utility of 1JC−H for assessing σ‐donation in structurally similar carbenes, while revealing its constraints for carbenes with ...
Radhika Gupta, Gilles Frison
wiley   +1 more source

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