Results 41 to 50 of about 40,715 (135)

Pd[B(S2O7)2]2 and Pd[B(SO4)(S2O7)]2: Two Borosulfates with Pd2+ in Cctahedral and one with Pd2+ in Square Planar Oxygen Coordination

Chemistry – A European Journal, Accepted Article.
The reaction of elemental palladium with B2O3 and SO3 at elevated temperature results in the formation of blue crystals of Pd[B(S2O7)2]2. Dependent on the reaction conditions, the compound crystallizes in two different polymorphs obtained as bulk samples.
Stefan Sutorius, David Patrun, Arthur Edelmann, Lars Schumacher, Rainer Pöttgen, Markus Suta, Jörn Bruns   +6 more
wiley   +1 more source

Oxidative Dehydrogenation of N‐Heteroaromatic Alkyl Alcohols and Amines Facilitated by Dearomative Tautomerization

Chemistry – A European Journal, Accepted Article.
The oxidation of alcohols, amines, and halides is a fundamental transformation in organic chemistry with significant applications in the synthesis of fine chemicals, pharmaceuticals, and natural products. Here we show that a broad variety of N‐heteroarenes bearing hydroxymethyl, aminomethyl, or halomethyl groups are oxidatively dehydrogenated to their ...
Omid Ghasemloo, Carson L. Hasselbrink, Douglas D. Cardona, Brenton DeBoef, Dugan Hayes   +4 more
wiley   +1 more source

N,N‐Bis(trifluoromethyl)aminoacetonitrile: A Versatile Building Block for the Introduction of the Bis(trifluoromethyl)amino Group

Chemistry – A European Journal, Accepted Article.
N,N‐Bis(trifluoromethyl)aminoacetonitrile (CF3)2NCH2CN (1) that is accessible via a simple single‐step protocol is establish­ed as building block for the introduction of the (CF3)2N group. The two reaction sites of 1, the methylene unit and the nitrile (cyano) group, provide access to different organic substance classes.
Kristina A. M. Maibom, Christoph Breitenstein, Sabine Lorenzen, Tanja Knuplez, Leon N. Schneider, Younes B. J. Bejaoui, Johannes Gierling, Krzysztof Radacki, Holger Braunschweig, Carl Deutsch, Min Shan, Thomas Fuchß, Michael Schulte, Nikolai Ignat'ev, Maik Finze   +14 more
wiley   +1 more source

Single GAF Domain Phytochrome Exhibits a pH‐Dependent Shunt on the Millisecond Timescale

ChemPhysChem, Volume 26, Issue 6, March 15, 2025.
During their light‐induced photocycle, phytochromes can engage in a thermal reversion back to the initially excited state, denoted as a shunt. This study investigates a pH‐dependent shunt transition in the Pfr state of the All2699g1 phytochrome from Nostoc punctiforme using UV/Vis laser flash photolysis and kinetic modeling. The findings suggest a keto‐
Florian Trunk, Lisa Köhler, Tobias Fischer, Wolfgang Gärtner, Chen Song, Chavdar Slavov, Josef Wachtveitl   +6 more
wiley   +1 more source

Elucidating the structures of substituted adamantyl esters and ethers using rotational spectroscopy and computations

ChemPhysChem, Accepted Article.
Adamantane derivatives are promising candidates in the design of new materials with unique properties. In this study, we investigated the molecular structure of a series of adamantyl esters and ethers with an increasing substituent size using broadband rotational spectroscopy.
Nataša Burić, Donatella Loru, Jasna Alić, Marina Šekutor, Melanie Schnell, Pablo Pinacho   +5 more
wiley   +1 more source

Unveiling Correlations in Metal‐Organic Interface Properties: A Computational Exploration of Alternant and Non‐Alternant π‐Electron Systems

ChemPlusChem, EarlyView.
The properties of metal‐organic interfaces are important for the performance of organic electronic devices. The adsorption of alternant and non‐alternant polycyclic conjugated hydrocarbons on Cu(111) was modeled using first‐principle DFT calculations. The difference in interface properties between physisorption and chemisorption is shown and relations ...
Jakob Schramm, Ralf Tonner‐Zech
wiley   +1 more source

Spectroscopic Investigations of a Vandalized Contemporary Acrylic Painting on Canvas Using Model Paintings and Chemometrics

ChemPlusChem, Accepted Article.
The characterization and conservation of materials constituting contemporary art pose a significant challenge for scientists and restorers due to the wide variability and heterogeneity in their compositions and their chemical instability. The aim of this study is to contribute to the understanding of the composition and ageing of materials in ...
Jana Striova, Silvia Innocenti, Arianna Ingrassia, Moira Bertasa, Barbara Salvadori   +4 more
wiley   +1 more source

Diazonium Salts in Visible Light Photocatalysis – a Focused Overview of their Application in Continuous Flow Synthesis

ChemPhotoChem, EarlyView.
The combination of continuous flow technology and visible light photocatalysis has been used to improve the safety and productivity of reactions with diazonium salts as reactive intermediates. This approach has proven to be a reliable method for various organic synthesis routes with diazonium salts under mild and well‐defined conditions.
Christoph Deckers, Thomas H. Rehm
wiley   +1 more source

Physics‐based inverse modeling of battery degradation with Bayesian methods

ChemSusChem, Accepted Article.
To further improve Lithium‐ion batteries (LiBs), a profound understanding of complex battery processes is crucial. Physical models offer understanding but are difficult to validate and parameterize. Therefore, automated machine‐learning methods (ML) are necessary to evaluate models with experimental data. Bayesian methods, e.g., Expectation Propagation
Micha Philipp, Yannick Kuhn, Arnulf Latz, Birger Horstmann   +3 more
wiley   +1 more source

En Route Toward Sustainable Polycarbonates Via Large Cyclic Carbonates

ChemSusChem, Accepted Article.
This review reports an up‐to‐date overview of the synthetic methodologies developed for the preparation of large cyclic organic carbonates with ≥ 6‐membered rings (6M‐CCs and above), highlighting the most sustainable synthetic pathways employing diols (including renewable‐based ones) and non‐hazardous carbonyl sources, e.g., linear organic carbonates ...
Francesco Della Monica, Arianna Brandolese, Graziano Di Carmine, Maurizio Selva, Giulia Fiorani, Lorella Izzo   +5 more
wiley   +1 more source