Results 61 to 70 of about 6,031,312 (184)

Isolation and Reactivity of a Square‐Planar Trisamido Silane

Angewandte Chemie International Edition, EarlyView.
We report the synthesis and comprehensive characterisation of a square‐planar Si(+IV) hydride supported by an unsymmetric, trianionic and dearomatised N,N,N‐pincer ligand. This system enables element–ligand cooperative reactivity as an alternative to silicon‐centred redox chemistry, illuminating a largely unexplored regime in high‐valent silicon ...
David M. J. Krengel, Xiaobai Wang, Christopher Golz, Regine Herbst‐Irmer, Oliver P. E. Townrow, Malte Fischer   +5 more
wiley   +1 more source

Asymmetric Fe–Te Pairs Enhance Peroxymonosulfate Activation via Surface‐Bound Hydroxyl Radicals Pathways

Angewandte Chemie International Edition, EarlyView.
An asymmetric Fe–Te dual‐atom pair directs peroxymonosulfate activation toward long‐lived surface‐bound hydroxyl radicals through strong p–d hybridization. The resulting electronic asymmetry enables efficient pharmaceutical degradation and reveals a metal–metalloid pairing strategy for steering reactive oxygen species pathways in advanced oxidation ...
Xuheng Li, Chunli Wang, Yuntong Sun, Sheng Wang, Min Zheng, Tierui Zhang, Jong‐Min Lee   +6 more
wiley   +1 more source

Forcing the Side‐on π‐Coordination of a C≡C Triple Bond to Technetium Using the As,CC,As Alkyne Pincer Ligand 1,2‐Bis(2‐(diisopropylarsaneyl)‐4‐(trifluoromethyl)phenyl)Ethyne

Angewandte Chemie International Edition, EarlyView.
Technetium alkyne complexes have eluded isolation for decades with the only indicators for their existence being the isolation of vinylidene carbenes or their follow‐up reaction products despite plentiful of reports for neighboring elements. Stable, crystalline Tc(III) and Tc(V) alkyne complexes (and their Re analogs) have now been prepared and fully ...
Maximilian Roca Jungfer, Moritz Johannes Ernst, Lukas Eberle, Marius Kesselring, Guilhem Claude, Joachim Ballmann   +5 more
wiley   +1 more source

Harnessing ferroptosis from multilayer defense networks to nanoplatforms for specific cancer therapy

BMEMat, EarlyView.
Nanomaterials target metabolically‐regulated ferroptosis for cancer therapy. Iron‐based or alternative nanoplatforms integrate ferroptosis with chemotherapy, immunotherapy, or radiotherapy. They enable stimulus‐responsive therapies (photothermal, photodynamic, sonodynamic) activated by near‐infrared, light, or ultrasound, achieving potent synergistic ...
Xinyue Xu, Xuejian Wang, Wenyan Jiang, Wan Hairul Anuar Kamaruddin, Chunyan Fang, Pengfei Zhang   +5 more
wiley   +1 more source

From Two‐Electron to Four‐Electron System: Electrolyte Regulation for Advanced Aqueous Zn–I2 Batteries

Carbon Energy, EarlyView.
This review systematically summarizes recent progress in electrolyte‐regulated aqueous Zn–I2 batteries (AZIBs). It outlines the fundamentals of AZIBs along with their main challenges, and then analyzes electrolyte‐engineering strategies that improve both two‐ and four‐electron reactions.
Yucong Wang, Ruifeng Huang, Zhangchi Yang, Shaojian Zhang, Lijing Yan, Weijie Chen, Xiaolong Lin, Yongjun Li, Shuxing Wu, Zhan Lin, Jun Lu   +10 more
wiley   +1 more source

Recent Strategies Toward Durable and Ion‐Tolerant Transition Metal‐Based Electrocatalysts in Seawater Electrolysis

Carbon Energy, EarlyView.
Recent strategies address these challenges through ion‐specific regulation, encompassing chloride‐tolerant and chloride‐regulating anodes together with cathode designs that suppress OH− accumulation and Mg2+/Ca2+ coupling. This ion‐management‐oriented framework provides general guidelines for achieving stable, selective, and scalable seawater ...
Lina Li, Wenda Zhang, Xinti Yu, Ning Han, Zhangxing Chen, Heng Zhao   +5 more
wiley   +1 more source

Functionalizing Conductive Diamond: Recent Advance in Fabrication, Modifications, and Applications

Carbon Energy, EarlyView.
This review highlights recent advancements in the synthesis, modification, and electrochemical applications of conductive diamond, particularly boron‐doped diamond (BDD). It emphasizes progress in fabrication methods, including CVD and HPHT, and explores modifications such as doping, surface terminations, and composite design, enabling significant ...
Ning Linghu, Xin Jiang, Jing Xu
wiley   +1 more source

Electronic Resonance Network Stabilized Crystal Structure in High‐Nickel Cathodes for Lithium‐Ion Batteries

Carbon Energy, EarlyView.
Transition metal (TM) ions with empty eg orbitals induce single‐electron delocalization in Ni3+ to form the resonance structure of Ni─OO─TM through the high‐entropy effect. High‐nickel cathode materials with electron resonance structure have the advantages of improving thermodynamic stability, suppressing phase transitions, and mitigating lattice ...
Yi Li, Qinwen Cui, Jinpeng Li, Xingyu Li, Liang Yin, Erhong Song, Youwei Wang, Xiaolin Zhao, Jianjun Liu   +8 more
wiley   +1 more source

Recent Progress on Fullerene–Based Functional Materials for Energy Conversion

Carbon Energy, EarlyView.
A schematic illustration summarizing the classification, and photo‐/electro‐‐/thermo‐catalysis and energy storage applications of C60 and derivatives. ABSTRACT Efficient energy conversion and environmental protection are still constrained by rapid carrier recombination, unstable interfaces, limited active site, and so on. Owing to the unique electronic
Ying Jiang, Bo Wu, Chunru Wang
wiley   +1 more source

Selective Oxidation Strategies for Cost‐Efficient Green Hydrogen Production via Hybrid Water Electrolysis

Carbon Energy, EarlyView.
Hybrid water electrolysis has emerged as a promising alternative to conventional electrolysis for sustainable hydrogen production. The economic potential of replacing water oxidation with organic substrates is assessed. For each substrate, representative electrocatalysts and mechanistic insights are reviewed to identify design principles for optimized ...
Conor Brennan‐Pollak, Lua Henderson, Cian Clarke, Maida A. Costa de Oliveira, Dídac A. Fenoll, Sreedhanya Pallilavalappil, Aswathy Babu, Shaista Jabeen, Pranav K. Gangadharan, Huabin Zhang, Suresh C. Pillai, Paula E. Colavita, Max García‐Melchor   +12 more
wiley   +1 more source