Results 61 to 70 of about 6,698 (198)

Cooperative Redox Catalysis of N2O Decomposition by Short‐Range RhOx and CeOx Anchored to Co3O4

Angewandte Chemie International Edition, EarlyView.
A short‐range Rh–O–Co–O–Ce interfacial moiety drives low‐temperature N2O decomposition via a cooperative redox cycle. Operando modulated‐excitation XAS with phase‐sensitive detection (ME‐XAS + PSD) tracks rapid, reversible Rh oxidation coupled to Co reduction.
Daniel C. Cano‐Blanco, Silvio Bellomi, Daniele Bonavia, Ivo Alxneit, Kirill A. Lomachenko, Karin Föttinger, Oliver Kröcher, Davide Ferri   +7 more
wiley   +1 more source

Erwin Schrödinger und die Versuchungen der (Wissenschafts‐)Biografik: Vorurteilsgefüge und Mechanismen der Skandalisierung

Berichte zur Wissenschaftsgeschichte, EarlyView.
Since late 2021, serious allegations have been made against physicist Erwin Schrödinger, ranging from pedophilia to serial sexual abuse. These accusations have significantly tarnished the Nobel Prize winner's public reputation. The ongoing debate has repeatedly raised the question of whether, and to what extent, these grave allegations are justified ...
Magdalena Gronau, Martin Gronau
wiley   +1 more source

Photochemistry of Aromatic N‐Oxides in Water Probed by Time‐Resolved X‐ray Absorption Spectroscopy

Chemistry – A European Journal, EarlyView.
Time‐resolved XAS at the nitrogen and oxygen K‐edges is applied to the photorearrangement of two N‐oxides in water. Pyridine N‐oxide rapidly forms the oxaziridine isomer. Pyridazine N‐oxide undergoes ring opening to the diazo compound, without any evidence of intermediates.
Maximilian Paradiz Domínguez, Robby Büchner, Mattis Fondell, Albert M. Brouwer   +3 more
wiley   +1 more source

Energy Balancing of Electrochemical Alternatives to the Solvay Process

Chemie Ingenieur Technik, EarlyView.
To overcome the CaCl2 and CO2 emissions custom to the conventional Solvay process in soda ash production, electrochemically based alternatives were investigated. In particular, the mass‐ and energy balances for chlor‐alkali electrolysis and bipolar electrodialysis‐based processes are discussed comprehensively in the presented work.
Tom Wenzel, Holger Kryk, Stefan Fogel, Sebastian Felix Reinecke   +3 more
wiley   +1 more source

A Short‐Cut Design Approach to Evaluate Reboiler Designs in Vapor Recompression Scenarios

Chemie Ingenieur Technik, EarlyView.
A short‐cut model framework that incorporates mechanical vapor recompression (MVR) requirements into reboiler design is presented, which is particularly beneficial during early process development with limited data or initial feasibility assessments.
Franziska Lais, Stephan Scholl, Katharina Jasch   +2 more
wiley   +1 more source

Nichtlineare Staubungsneigung binärer Schüttgutmischungen: Herausforderungen bei der Prognose Non‐linear dusting tendency of binary bulk material mixtures: Challenges in prognosis

Chemie Ingenieur Technik, EarlyView.
Aufgrund überlagerter oder konkurrierender Mechanismen sind relevante Wechselwirkungen bei der Staubung von Schüttgutmischungen komplex und nur unzureichend verstanden. Selbst für Mischungen aus umfassend charakterisierten Einzelkomponenten existieren keine belastbaren Modelle. In dieser Arbeit werden die Hürden bei der Prognose thematisiert.
David Horst, Anke Helfer, Eberhard Schmidt   +2 more
wiley   +1 more source

Vanadium dioxide thin films integrated with printed circuit board enables low-cost, reconfigurable millimeter-wave devices

Communications Engineering
Millimeter-wave switches are essential for reconfigurable and adaptive communication systems, yet current solutions often face trade-offs between performance, scalability, and cost. Here we present a scalable, high performance and cost-effective approach
Amir Afshani, Wenqiang Xiang, Tarek Djerafi, Mohamed Chaker   +3 more
doaj   +1 more source

Matching Heat Pump Configurations and Process Parameters for Cost‐Minimal Heat‐Integrated CO2 Capturing Process

Chemie Ingenieur Technik, EarlyView.
In a CO2 absorption process, it is investigated whether the adjustment of operating parameters facilitates the integration of different closed heat pump cycles considering various refrigerants. The influence of different integration concepts and electricity prices are investigated by means of resulting total annual costs.
Johannes Wloch, Marcus Grünewald, Julia Riese   +2 more
wiley   +1 more source

Reshaping the phonon energy landscape of nanocrystals inside a terahertz plasmonic nanocavity

Nature Communications, 2018
Here the authors show that the dipole-active phonon resonance of semiconducting nanocrystals can be hybridized by a strongly concentrated terahertz vacuum field of a plasmonic nanocavity, thus achieving strong plasmon–phonon coupling even in the absence ...
Xin Jin, Andrea Cerea, Gabriele C. Messina, Andrea Rovere, Riccardo Piccoli, Francesco De Donato, Francisco Palazon, Andrea Perucchi, Paola Di Pietro, Roberto Morandotti, Stefano Lupi, Francesco De Angelis, Mirko Prato, Andrea Toma, Luca Razzari   +14 more
doaj   +1 more source

Method for the Ecological and Economic Assessment of Mechanical Vapour Recompression in the WindaB Tool

Chemie Ingenieur Technik, EarlyView.
Method to assess economic and ecologic advantages of mechanical vapour recompression at early stage of development. Main correlations between design parameters and profitability as well as CO2 emission reductions are described shown in a case study of methanol–water.
Hannes Schneider, Stephan Scholl, Mandy Paschetag   +2 more
wiley   +1 more source