New Sintanyl Phosphonates for Protection of Oil and Gas Pipelines from Steel Corrosion [PDF]
Many corrosion inhibitors are economically disadvantageous or toxic to the environment. Additionally, there are certain requirements for corrosion inhibitors.
Nikitin, Evgeny +4 more
core +1 more source
Synthesis of β‐Aryl‐α,β‐Dehydroaminophosphonates by Pd‐Catalyzed Fujiwara–Moritani C−C Coupling
β‐aryl‐N‐acetyl‐α,β‐dehydroaminophosphonic esters can be synthesized through oxidative Fujiwara–Moritani C−C coupling of different arenes with diethyl α,β‐dehydroaminophosphonate 1, process catalyzed by Pd2+ and assisted by Ag+. The reaction is regioselective to the E‐isomer and tolerates the presence of both electrodonating and electronwithdrawing ...
Javier Sáez +3 more
wiley +1 more source
Addition and cycloaddition reactions of Phosphinyl- and Phosphonyl-2H-Azirines, Nitrosoalkenes and Azoalkenes [PDF]
An overview of the use of 2H-azirines, conjugated nitrosoalkenes and conjugated azoalkenes bearing phosphorus substituents in addition and cycloaddition reactions is presented, focused on strategies for the synthesis of aminophosphonate and ...
Lemos, A.
core
On the discovery and development of tandem 1,4- and 1,2-addition of phosphites to 1-azadienes [PDF]
Over the past 15 years we have developed a one-step protocol for the synthesis of 3-phosphonylated aminophosphonates from alpha,beta-unsaturated imines through tandem 1,4-1,2-phosphite addition.
Debrouwer, Wouter +3 more
core +2 more sources
Asymmetric Organocatalyzed Synthesis of α‐Aminophosphinates via Thiourea Anion‐Binding Catalysis
P‐Stereogenic α‐aminophosphinates were obtained in high enantioselectivity via anion‐binding catalysis with thiourea catalysts, further expanding the range of nucleophiles that can be used in this type of catalysis. Abstract Thioureas catalyze the reaction of phosphonites with in situ‐generated isoquinolinium salts to give C and P‐stereogenic α ...
Cáoimhe J. Niland +3 more
wiley +1 more source
Omar M Ali,1 Mohammed T Alotaibi,1 Yasser H Zaki,2 Hamada H Amer3 1Department of Chemistry, University College of Turabah, Taif University, Taif, 21944, Saudi Arabia; 2Department of Chemistry, Faculty of Science, Beni-Suef University, Beni-Suef, 62514 ...
Ali OM, Alotaibi MT, Zaki YH, Amer HH
doaj
Tetramethylguanidine (TMG)-catalysed Synthesis of α-Aminophosphonates by a One-pot Reaction [PDF]
Aldimines (Schiff’s bases) undergo nucleophilic addition with diethyl/dimethyl/diphenylphosphite (Pudovik reaction) in the presence of a catalytic amount of tetramethylguanidine (TMG) at ambient temperature to afford the corresponding α-aminophosphonates
Kumar, BS +3 more
core +1 more source
Calcium Bromide Catalysed Synthesis and Anticoagulant Activity of Bis(α-aminophosphonates) [PDF]
A simple and efficient microwave irradiated synthesis of bis(α-aminophosphonates) has been developed by the reaction of 1,2-diphenylethane-1,2-diamine, aromatic aldehydes, and dimethyl phosphite in the presence of calcium bromide as catalyst under neat ...
Bakthavatchala Reddy, N. +6 more
core +1 more source
The use of metal compounds such as cisplatin and its derivatives as therapeutic and diagnostic agents against various diseases is well established. Although metallodrugs have been very successful clinically, low therapeutic selectivity and the potential toxicity of the metal compounds mandate the need for a continuous search for more efficient and ...
Ngonidzashe Ruwizhi +4 more
wiley +1 more source
Synthesis of Phosphonates in a Continuous Flow Manner [PDF]
The synthesis of dialkyl H-phosphonates and α-aminophosphonates was studied in a continuous flow microwave reactor. Depending on the conditions, the alcoholysis of dialkyl H-phosphonates could be fine-tuned towards the mixed and the fully transesterified
Bálint, Erika +4 more
core +1 more source

