Results 41 to 50 of about 2,339 (147)

Organocatalyzed Beckmann rearrangement of cyclohexanone oxime by trifluoroacetic acid in aprotic solvent [PDF]

open access: yes, 2008
The Beckmann rearrangement of cyclohexanone oxime to ε-caprolactam catalyzed by trifluoroacetic acid in aprotic solvents such as toluene, 1,2-dichloroethane, acetonitrile, benzonitrile, nitromethane and their mixtures is described.
A. Vavasori   +27 more
core   +2 more sources

3D Hydrogel Cell Cultures and Their Biomedical Applications

open access: yesAdvanced NanoBiomed Research, EarlyView.
The review highlights the advantages of hydrogel‐based 3D cell cultures over traditional 2D models. These hydrogels closely mimic natural cellular environments, improving research in tissue engineering, drug discovery, cancer studies, and neuroscience.
Tri Lan Thai   +7 more
wiley   +1 more source

Allergic Sensitization to Inhalant Allergens in the Upper Respiratory Tract—the B Cell Side

open access: yesAllergy, EarlyView.
ABSTRACT Allergic diseases are on the rise worldwide, driven by respiratory epithelial barrier dysfunction that promotes sensitization to inhalant allergens such as pollen, dust mites, pet dander, and fungal spores. These antigens trigger IgE‐mediated immune responses that lead to diseases such as allergic rhinitis (AR) and asthma.
Ola Grimsholm   +9 more
wiley   +1 more source

Reactive microencapsulation of carbon allotropes in polyamide shell-core structures and their transformation in hybrid composites with tailored electrical properties

open access: yeseXPRESS Polymer Letters, 2016
Polyamide 6 microcapsules (PAMC) loaded with 2–10 wt% of different carbon allotropes: carbon black, multiwalled carbon nanotubes, carbon nanofibers and graphite were synthesized via activated anionic polymerization (AAROP) of ε-caprolactam in solution ...
F. Oliveira   +4 more
doaj   +1 more source

Vapor phase beckmann rearrangement of cyclohexanone oxime over different ferrierite zeolite catalysts [PDF]

open access: yes, 2002
Ferrierite zeolite catalysts prepared using different procedures have been tested for their activity for vapor phase Beckmann rearrangement of cyclohexanone oxime to ε -caprolactam.
Anand, R.   +3 more
core   +1 more source

The plasticisation model of dye diffusion: Part 5

open access: yesColoration Technology, EarlyView.
Abstract The findings presented in the previous part of the paper (Part 4) of the re‐evaluation of previously published data reported for the temperature‐dependent diffusion of an organic acid within nylon 6 film, desorption of three acid dyes from dyed nylon 66 fabric, diffusion of an acid dye within nylon 6 monofilaments and adsorption of a sulphur ...
Stephen M. Burkinshaw
wiley   +1 more source

Intrinsically Flame‐Retardant Polyamide 6 by Anionic Ring‐Opening Copolymerization with a Phosphorous‐Containing Comonomer

open access: yesMacromolecular Materials and Engineering
A three‐step synthetic route is established for the synthesis of a phosphorus‐containing ε‐caprolactam derivative, starting from cyclohex‐2‐enone and diphenylphosphinous chloride, followed by a Beckmann rearrangement. 2D NMR spectroscopy reveals that the
Carlo Pani   +14 more
doaj   +1 more source

The plasticisation model of dye diffusion: Part 7

open access: yesColoration Technology, EarlyView.
Abstract Re‐evaluation using the Williams‐Landel‐Ferry equation, of exhaustion/fixation/adsorption data previously reported for four classes of anionic dye onto three different types of wool substrate, revealed that thermally activated dyeing/desorption behaviour is governed by the thermally regulated structural relaxation times of the respective water‐
Stephen M. Burkinshaw
wiley   +1 more source

2,3,5,6-Tetrafluoro-[N-(3-aminopropyl)-ε-caprolactam]-4-pyridine

open access: yesMolbank
The title compound was synthesized at a near-quantitative yield using the nucleophilic aromatic substitution of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) with perfluoropyridine (PFP). The purity and structure were determined by NMR (1H, 13C, 19F), GC-EIMS,
Chadron M. Friesen   +2 more
doaj   +1 more source

Ignition activation energy of materials based on polyamide 6 [PDF]

open access: yes, 2016
This contribution is aimed to compare the values of the ignition activation energies of two types of polyamide – Slovamid 6 FRB and Slovamid GF 50 LTS.
Balog, Karol   +3 more
core   +2 more sources

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