The effect of hydrogen bonding on the π depletion and the π-π stacking interaction
Non-covalent interactions such as hydrogen bonding and π–π stacking are essential types of interactions governing molecular self-assembly. The π–π stacking ability of aromatic rings depends on the electron density of the π orbitals, which is affected by ...
Sundholm, D, Johansson, MP, Ahmed, U
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π-π stacking interactions: Non-negligible forces for stabilizing porous supramolecular frameworks. [PDF]
Sci Adv, 2020 Deng JH +6 more
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Exploiting π–π Stacking for Stretchable Semiconducting Polymers
, 2018 Although intermolecular charge transport is known to occur via π–π stacking, the influence of π–π stacking on the mechanical properties of polymers has received little attention compared with other dynamic noncovalent interactions. Herein, we demonstrate
Joohyeon Lee (4993043) +23 more
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π−π Interactions Affect Coordination Geometries
, 2016 We explore the effect of π−π interactions in the complexes of mercury halides containing the N-(naphthyl)-2-pyrazine carboxamide ligand (L1) in the coordination geometry of the central metal. Results show molecular packing features have a dramatic effect
Hamid Reza Khavasi (606027) +1 more
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2-Oxo-2H-chromen-4-yl 3,3-dimethylbutanoate
IUCrDataIn the crystal of the title compound, C15H16O4, the molecules are connected through C—H...O hydrogen bonds, generating [100] chains, which are crosslinked by weak π–π stacking interactions.
Valentin Bationo +4 more
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Anisotropy of π–π Stacking as Basis for Superlubricity
When two surfaces move against each other, often high adhesive strength with low friction is desired. Then, the interfacial interaction requires a strong directional anisotropy, as provided by π–π stacking.
Johanna L. Trefs (14247762) +3 more
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A special molecular association is π–π-stacking, driven by weak interactions within aromatic compounds. The π–π-stacking interactions can occur in either a sandwich-like or T-shaped manner. In this study, a method to recognise π–π-stacking from classical
Florisson, Sara +5 more
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, 2016 Parallel-displaced π−π stacking interactions have been known to be the dominant force in stabilizing the double helical structure of DNA and the tertiary structure of proteins.
Jin-Feng Jia (2161417) +10 more
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Density Functional Method Study on the Cooperativity of Intermolecular H-bonding and π-π+ Stacking Interactions in Thymine-[Cnmim]Br (n = 2, 4, 6, 8, 10) Microhydrates. [PDF]
Molecules, 2022 Wang Y +7 more
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Thiosemicarbazone Structures Including Nickelophilic Interaction as Well as Both Hydrogen Bonding and π-π Stacking Interactions: NLO, Electrochemical, Chromism, and Spectroelectrochemical Properties. [PDF]
ACS OmegaAvcu Altıparmak E +4 more
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