Direct Electrochemical Synthesis of Nickel (II) Thiolates and their Coordination Complexes. [PDF]
Metallo organic compounds can be synthesized electrochemically by anodic generation of metal cations by using sacrificial metal anode. Bis-thiolates complexes of Nickel, Ni(SR)2 have been prepared in an H-type cell by electrochemical oxidation of thiols ...
Baljit Singh +3 more
core +1 more source
Electrogenerated nickel(I) complexes as catalysts for the intramolecular radical cyclisation of unsaturated a-bromoesters [PDF]
The indirect electroreduction of unsaturated α-bromoesters using Ni(II) complexes as electron-transfer mediators is achieved in N,N'-dimethylformamide by constant current electrolysis between a cathode and a sacrificial anode in a diaphragmless cell ...
Medeiros, Maria José +3 more
core +1 more source
The phenomenon of prehistoric ritual pits: Several examples from the central Balkans [PDF]
In recent years, the phenomenon of pits with special deposits, i.e. ritual pits, seems to have, once again, attracted attention both in Europe and in the Balkans.
Bulatović Aleksandar P.
doaj +1 more source
Clean production of renewable fuels is a great challenge of our scientific community. Iridium complexes have demonstrated a superior catalytic activity in the water oxidation (WO) reaction, which is a crucial step in water splitting process.
Giordano Gatto +4 more
doaj +1 more source
Development of Visible-Light Driven Cu(I) Complex Photosensitizers for Photocatalytic CO2 Reduction
The visible-light responsive Cu(I)-complex photosensitizers were developed by introducing various aromatic substituents at the 4,7-positions of a 2,9-dimethyl-1,10-phenanthroline (dmp) ligand in a heteroleptic CuI(dmp)(DPEphos)+-type complexes (DPEphos =
Hiroyuki Takeda +4 more
doaj +1 more source
Efficient Light‐Driven Water Oxidation Catalysis by Dinuclear Ruthenium Complexes [PDF]
Mastering the light-induced four-electron oxidation of water to molecular oxygen is a key step towards the achievement of overall water splitting to produce alternative solar fuels.
Neudeck, Sven +14 more
core +1 more source
Study of peptide on-line complexation with transition-metal ions generated from sacrificial electrodes in thin-chip polymer microsprays [PDF]
A miniaturized polymer electrospray-type interface is used to study metal-ion chelation with model peptides. Taking advantage of the intrinsic electrochemical behavior of electrospray, a sacrificial electrode is used to generate at the same time ...
Rohner, T. C., Girault, H. H.
core +1 more source
Bimetallic Iridium-Carbene Complexes with Mesoionic Triazolylidene Ligands for Water Oxidation Catalysis [PDF]
Two new diiridium–triazolylidene complexes were prepared as bimetallic analogues of established mononuclear water oxidation catalysts. Both complexes are efficient catalyst precursors in the presence of cerium ammonium nitrate (CAN) as sacrificial ...
Woods, James A. +3 more
core +2 more sources
The article publishes a warrior burial from the Southern Urals. In the kurgan with specific features of the South Ural nomads’ elite burial rite, a central dromos with an individual burial of a nomadic military nobility representative was studied. In the
Sergey V. Sirotin +2 more
doaj +1 more source
Iron Polypyridyl Complexes for Photocatalytic Hydrogen Generation [PDF]
A series of Fe(III) complexes were recently reported that are stable and active electrocatalysts for reducing protons into hydrogen gas. Herein, we report the incorporation of these electrocatalysts into a photocatalytic system for hydrogen production ...
Ryan J. DiRisio (3068823) +4 more
core +1 more source

