In this work, density functional theory (DFT) calculations were employed to study the photocatalytic reduction of CO2 into CO using a series of Pt(II) square planar complexes with the general formula [Pt(5-R-dpb)Cl] (dpb = 1,3-di(2-pyridyl)benzene anion,
Antonia Sarantou, Athanassios Tsipis
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Cobalt, nickel, and iron complexes of 8-hydroxyquinoline-di(2-picolyl)amine for light-driven hydrogen evolution [PDF]
Novel cobalt, nickel, and iron complexes based on the pentadentate 8-hydroxyquinoline-di(2-picolyl)amine ligand were synthesized and thoroughly characterized. X-ray structures of both the cobalt and iron complexes were also obtained, showing the tendency
LICINI, Giulia Marina +18 more
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The effect of metal ligands on the adsorption of metal coordination complexes on polystyrene nano-beads [PDF]
Nanostructured metal oxides showing geometrically controlled shape are often shaped by the calcination of selected metal coordination complexes adsorbed on sacrificial polystyrene beads (PSB) in aqueous suspensions.
L Ortolani (13546378) +6 more
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Towards photoinduced charge accumulation in purely molecular D⁶ metal complexes with oligo-triarylamine donors [PDF]
One major problem humanity faces these days is the use of fossil fuels and even more pressing, the consequences of their combustion. Therefore, multiple research groups of various scientific backgrounds have made it their business to find a way to ...
Bonn, Annabell G.
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The influence of the sacrificial anode nature on the mechanism of electrochemical arylation and alkylation of white phosphorus [PDF]
The material of the sacrificial anode has a substantial effect on the nature and yield of the target products of electrochemical phosphorylation of organic halides by white phosphorus in the presence of the nickel complexes with 2,2′-bipyridine.
Sinyashin O. +3 more
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In this study, we present a novel multicomponent self‐assembly approach that offers good potential for crafting heterometallic complexes with exceptional constitutional control.
Yijia Liu +5 more
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The impeding effect of dissolved oxygen on the photocatalytic reduction of [PdCln(H2O)4−n]2−n (n = 0–4) complexes employing different TiO2 photocatalysts in the absence of an added sacrificial reducing agent [PDF]
The photocatalytic reduction of chloro-aqua palladium(II) complexes, [PdCln(H2O)4−n]2−n (n = 0-4), as a means of palladium metal recovery and waste water purification, was investigated employing four different titanium dioxide samples in a batch reactor.
Kriek, R.J., Mahlamvana, F.
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Influence of Electron Transfer Mediators in the Pd(II)-Catalyzed Oxidative Carbonylation of Aniline
Currently, the most promising alternative to the use of the phosgenation reaction, for large-scale production of isocyanates, ureas, and carbamates, appears to be the Pd-catalyzed oxidative carbonylation of arylamines.
Andrea Vavasori +3 more
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Efficient light-driven water oxidation catalysis by dinuclear Ru complexes [PDF]
Mastering the light-induced four-electron oxidation of water to molecular oxygen is a key step towards the achievement of overall water splitting to produce alternative solar fuels.
L. Francàs, Laia +6 more
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Polynuclear Cobalt Complexes as Catalysts for Light-Driven Water Oxidation: A Review of Recent Advances [PDF]
Photochemical water oxidation, as a half-reaction of water splitting, represents a great challenge towards the construction of artificial photosynthetic systems.
Dmytro S. Nesterov, Oksana V. Nesterova
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