Results 21 to 30 of about 1,188,112 (167)

Biomass‐Engineered Defect‐Rich g‐C3N4 Anchors Pd2+‐Rich Ultrafine Particles for Highly Efficient Formic Acid Dehydrogenation

open access: yesRare Metals, Volume 45, Issue 4, April 2026.
ABSTRACT Formic acid (FA) is considered to be a safe and convenient hydrogen source; however, achieving controlled and efficient FA dehydrogenation under mild conditions using stable solid catalysts remains a significant challenge. Pd‐based catalysts have been extensively studied due to their superior catalytic activity to other metal catalysts.
Shuai Wei   +10 more
wiley   +1 more source

Ionic‐Liquid‐Assisted Synthesis of NiTe/CoTe Heterostructure With Te Vacancies in N, P, and F Co‐Doped Hollow Carbon Nanorods for Efficient Alkaline Hydrogen Evolution and High‐Performance Flexible Supercapacitors

open access: yesRare Metals, Volume 45, Issue 3, March 2026.
ABSTRACT Low conductivity, slow ion‐diffusion, and limited reactive sites are common problems in electrocatalysts and electrode materials. In this study, a complex NiTe–CoTe heterojunction with abundant Te vacancies embedded in N, P, and F co‐doped hollow carbon nanorods (NiTe1−x–CoTe1−x/NPFC) was fabricated via a simple ionic liquid‐assisted ...
Mingjie Yi   +7 more
wiley   +1 more source

Precise Tailoring of the Coordination Environment of Single‐Atom Cu(I) on Trifurcate AlL3 Supports for Click Chemistry

open access: yesRare Metals, Volume 45, Issue 3, March 2026.
ABSTRACT Single‐atom catalysis hinges on fundamental challenges in precisely controlling metal‐support interactions and rationally regulating metal–adsorbate relationships. Herein, we report a universal strategy for constructing highly efficient and well‐defined Cu(I) single‐atom catalysts based on a trifurcate AlL3 molecular support.
Donghui Zhang   +9 more
wiley   +1 more source

Bimetallic Mo/Fe‐Doped CoP2 Nanoleaf Array as a Bifunctional Electrocatalyst for Overall Water Splitting

open access: yesRare Metals, Volume 45, Issue 3, March 2026.
ABSTRACT The development of efficient and stable bifunctional catalysts remains a key challenge for green hydrogen production via electrochemical water splitting. In this study, a bimetallic Mo/Fe‐doped CoP2 nanoleaf array anchored on carbon cloth (Mo, Fe‐CoP2@CC) was synthesized from zeolitic imidazolate framework‐L (ZIF‐L) via an ion‐exchange and low‐
Xiangqun Zeng   +6 more
wiley   +1 more source

沸石负载TiO2光催化剂的制备及光催化降解染料废水的研究

open access: yesGongye shui chuli, 2013
制备了天然斜发沸石负载TiO2光催化剂,以染料活性黑溶液为降解目标物,紫外光为光源,在超声波协同作用下光催化降解染料废水,对催化剂的合成条件、催化活性及其重复使用性进行了研究。结果表明,在200℃焙烧温度下,由钛酸四丁酯与斜发沸石复合制备的催化剂具有最大的光催化活性,且其催化活性与纯TiO2相近。制备的催化剂质量稳定,可重复使用。超声波-光催化协同作用对染料的脱色率好于单一的光催化降解作用。
李琰   +5 more
doaj  

Non‐Precious Metals Enhance Hydrogen Evolution in COF/Cd0.9Cu0.1S S‐Scheme Heterojunctions: KPFM Reveals Charge Transfer Pathways

open access: yesRare Metals, Volume 45, Issue 3, March 2026.
ABSTRACT Photocatalytic hydrogen production from water splitting is a promising strategy for sustainable and clean energy generation. However, the design of low‐cost, highly active photocatalysts remains a critical challenge. In this study, covalent organic frameworks (COFs) were loaded onto the surface of Cd0.9Cu0.1S to fabricate COF/Cd0.9Cu0.1S ...
Yue Zhao   +3 more
wiley   +1 more source

PW/MCM-41光催化性能研究

open access: yesGongye shui chuli, 2011
以浸渍法制备了负载型光催化剂PW/MCM-41,并对催化剂进行了表征,考察了催化剂在光催化模拟染料废水亚甲基蓝(MB)溶液降解反应中的催化活性。实验结果表明:催化剂负载量为30%、催化剂投加质量浓度为3.0 g/L、MB溶液的初始质量浓度为10 mg/L、pH=5、光照时间100 min时,对亚甲基蓝降解率可达91%以上,且催化剂可重复使用。
黄艳芹, 程玉良, 周建伟
doaj  

染料敏化TiO2光催化剂的研究进展

open access: yesGongye shui chuli, 2021
TiO2光催化剂因其耐用性、低成本、低毒性、超亲水性以及出色的化学稳定性,广泛应用于水中有机污染物的降解。但TiO2的带隙(3.2 eV)较宽,导致TiO2的光生电子-空穴对易复合,无法充分利用可见光,限制了其实际应用。染料敏化可将TiO2的光响应范围扩展到可见光区域,提高其光催化活性。综述了染料敏化TiO2光催化剂的原理、染料敏化剂的分类、不同染料敏化剂的应用现状及效果,以期为染料敏化在TiO2光催化剂中的应用提供参考。
汤晓蕾, 董延茂, 袁妍, 杨雨杰
doaj  

Synergy of Built‐In Electric Field and Surface Reconstruction of Co–NiS/Ni3S2 Nanowires for Enhanced Bifunctional Activity and Anti‐Chlorine Corrosion in Seawater Electrolysis

open access: yesRare Metals, Volume 45, Issue 3, March 2026.
ABSTRACT The development of efficient and stable bifunctional electrocatalysts is a key challenge for the industrialization of hydrogen production by water electrolysis. In this work, Co‐doped NiS/Ni3S2 heterostructured nanowire arrays (Co–NiS/Ni3S2 NA) were successfully constructed by precisely modulating the phase‐selective behavior of nickel ...
Xing‐Hang Liu   +2 more
wiley   +1 more source

TiO2-Ca (OH)2-石墨的制备与光催化降解染料废水

open access: yesGongye shui chuli, 2018
将采用溶胶-凝胶法制备的光催化剂TiO2-Ca(OH)2与石墨机械研磨制备了新型复合光催化剂TiO2-Ca(OH)2-石墨。运用XRD、SEM、PL等手段对制备的新型复合光催化剂进行了表征,并对影响太阳光下光催化降解茜素红效果的因素进行了考察。结果表明,复合光催化剂TiO2-Ca(OH)2-石墨具有较好的光催化降解效果,在其质量比为1:0.02:0.006的光催化体系中,茜素红去除率可达99.65%。TiO2-Ca(OH)2-石墨中的各组分具有显著的协同效应。
饶砚迪   +4 more
doaj  

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