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超声辅助气液微萃取-气相色谱-质谱法测定海带中16种多环芳烃
Chinese Journal of Chromatography基于超声辅助气液微萃取(UA-GLME)联用气相色谱-质谱(GC-MS)技术,建立了测定海带中16种多环芳烃(PAHs)的检测方法,并对样品前处理和色谱条件进行了优化。海带样品用二氯甲烷-正己烷(1∶1,v/v)混合溶剂超声辅助提取后,经过气液微萃取技术进一步萃取,采用DB-5MS毛细管柱(30 m×0.25 mm×0.25 µm)分离,使用全扫描(SCAN)、选择离子监测(SIM)模式进行检测分析。结果表明,本方法在最优的条件下,PAHs在5.0~2 000 ng/mL范围内具有良好的线性关系 ...
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