Results 81 to 90 of about 25,302 (204)

Theoretical Study on Bonding and Catalytic Properties of N-heterocyclic Carbenes and Aluminum Carbenoids [PDF]

open access: yes, 2016
氮杂环卡宾(N-heterocycliccarbene,NHC)中sp2杂化的卡宾碳具有独特的σ2π0电子结构,表现出较强的σ给电子能力和一定的π电子接受能力。作为σ型的配体,NHC可以与过渡金属(Transitionmetal,TM)原子相互作用形成σ-型配合物,并导致过渡金属中心呈现出富电子特征,使其在催化反应中具有较高的反应活性。强亲核性的NHC进攻醛,可以使其由亲电试剂反转为亲核试剂,所产生的Breslow中间体具有较高的反应活性,能与多种亲电试剂发生丰富的化学反应。当醛上具有不饱和共轭链时 ...
张向飞
core  

管式反应器液相循环反应制备二甘醇乙烯基醚 [PDF]

open access: yes, 2018
以乙炔和二甘醇为原料,二甘醇钾为催化剂,采用管式反应器液相循环反应制备二甘醇乙烯基醚。研究了催化剂用量、反应温度、反应压力和停留时间等因素对乙炔转化率的影响,得到较为适宜的反应条件为:催化剂二甘醇钾用量为二甘醇质量的4%、反应温度175℃、反应压力6MPa、停留时间175s。在该条件下进行了液相连续循环反应,反应达到稳态时,二甘醇的转化率为76.03%,二甘醇单乙烯基醚收率为59.03%,二甘醇双乙烯基醚的收率为15.10%,合计二甘醇乙烯基醚总收率为74.13 ...
黄心权, 黎四芳
core   +1 more source

Cobalt‐Based Metal Hybrid Encapsulated Micro‐Aluminum for Tailoring Combustion in Composite Solid Propellants

open access: yesRare Metals, Volume 45, Issue 4, April 2026.
ABSTRACT To address the issues of aluminum (Al) powder agglomeration during combustion and low oxidizer decomposition efficiency in composite solid propellants, this study utilized in situ self‐assembly technology to prepare cobalt‐based hybrid‐coated modified Al powder (Al@CZ).
Chong Chen   +11 more
wiley   +1 more source

基于低碳教育的科技周活动项目开发

open access: yes野生动物学报, 2014
在人类生存环境不断恶化、能源紧缺与温室效应等问题日益突出的背景下,低碳生活已成为人类寻求自救的生活方式,低碳教育也越来越受到重视。在每年开展的科技周活动中,杭州动物园充分利用自身资源优势,发挥教育职能,遵循年龄化、生活化、活动化与体验式等原则,结合低碳教育主题有针对性地面向多个层次开展形式多样的活动,采用体验式学习模式、扮演角色参与情景剧、科学探索活动、科技作品展示、趣味科学游戏等,并走出园区深入学校与社区,为促进树立低碳意识和低碳生活的理念形成做出了较好的贡献。
蒋国红 胡新波 江 志
doaj  

Kinetics of the hydrocarbon generation process of marine source rocks in South China

open access: yesPetroleum Exploration and Development, 2010
The kinetics of hydrocarbon generation of different types of marine source rocks and planktonic algae in South China were analyzed using the Rock-Eval 6 instrument and the Optkin kinetic software.
Jiang Qigui   +4 more
doaj   +1 more source

Solution synthesis and characterization of nickel nanosheets [PDF]

open access: yes, 2016
具有形状各向异性的镍纳米晶在催化、磁记录、生物、电极材料等诸多领域具有重要的应用价值,因此探索一种简便可靠的合成方法来制备尺寸和形貌可控的镍纳米晶具有重要的研究意义。本论文通过有机液相法合成出了镍纳米片,研究了不同的制备参数对镍纳米晶的形貌、尺寸和结构的影响,并表征了其磁学性质和催化对硝基酚还原的性能。 本文首先以油胺作为溶剂和还原剂,乙酰丙酮镍作为镍前驱体,六羰基钨作为形核诱导剂,合成出了尺寸可控的镍纳米片。在较低的反应温度(160℃)和较短的保温时间下可以得到尺寸为15nm的镍纳米片 ...
汪志超
core  

The Role of Technology Standards in Strategic Hedging

open access: yesAsian Politics &Policy, Volume 18, Issue 2, April 2026.
ABSTRACT This article argues that technology standards provide Southeast Asian states with a distinct mechanism for hedging amid intensifying US–China technological rivalry. Traditional hedging strategies emphasizing economic engagement without political alignment are increasingly constrained by the weaponization of technological interdependence ...
Darren J. Lim, Anthea Roberts
wiley   +1 more source

青蒿琥酯对豚鼠气管平滑肌的影响

open access: yesZhongshan Daxue xuebao. Yixue kexue ban, 1997
摘 要 青蒿琥酯能松弛豚鼠气管平滑肌, 并能非竞争性拮抗乙酰胆碱、组织胺的缩气管作用。β 肾上腺 素受体阻断剂噻吗洛尔不能阻断青蒿琥酯的松驰气管作用;青蒿琥酯对豚鼠气管组织腺苷酸环化酶活性呈药 物浓度依赖性明显的激活作用。在一定剂量范围内, 药物浓度与酶的激活作用呈明显的线性关系。提示青蒿 琥酯松驰气管作用与激活腺苷酸环化酶有关。
秧茂盛 肖建初
doaj  

Studies on Preparation and Visible-light-induced Photocatalytic Properties of Bismuth-containing Nanocomposites [PDF]

open access: yes, 2016
如何提高光量子利用率和光量子效率是目前光催化材料研究中的两个关键问题。为了解决铋系半导体光催化剂光生载流子容易复合及其光量子利用率较低的问题,本文采用简单易行的静电纺丝技术与软化学原位合成技术,设计制备一系列分布均匀、能级匹配的铋系纳米复合材料,并围绕这些材料在光催化领域内的应用性能开展研究。在可见光光催化剂的设计和材料的控制合成方面取得了一定的进展,为今后类似材料体系的构筑提供了参考依据,所合成材料具有良好的应用前景。 (1)采用静电纺丝法和溶液原位离子交换法成功合成了Bi2S3 ...
邱英强
core  

Urban adults' engagement in nature education and its interplay with everyday lived experiences: A case study from Shenzhen, China

open access: yesPeople and Nature, Volume 8, Issue 3, Page 741-753, March 2026.
Abstract Currently, scholarship on education to foster connectedness with nature primarily focuses on children. As adults likewise face the disconnection from nature and play a key role in influencing children, it is important to understand how they perceive, engage in, and benefit from relevant programmes.
Xiaoxue Chen, Zuyi Lyu, Junxi Qian
wiley   +1 more source

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