Results 31 to 40 of about 537,120 (143)

一种光电复合检测溶氧的方法及实验装置 [PDF]

open access: yes, 2015
本发明公开一种光电复合检测溶氧的方法及实验装置,该方法包括以下步骤:(1)某一溶氧浓度水样中的溶氧透过透氧膜与聚苯胺膜层发生化学反应,引起聚苯胺膜层开路电压和介电常数的变化;(2)实时获取对应聚苯胺膜层开路电压和介电常数的电信号和光信号;(3)利用获取的电信号和光信号与水中溶氧浓度的对应关系,求得水样中溶氧的浓度。对应该方法的实验装置结构简单,操作方便、所采用的全内反射椭偏成像系统具有实时、高通量、高灵敏度的特点,能够实时对不同浓度溶氧的水样进行光电复合检测,解决了现有溶氧浓度检测方法或繁琐、费时 ...
李萌, 靳刚, 刘巍
core  

常压无溶剂双氧水氧化氯丙烯制环氧氯丙烷连续生产装置 [PDF]

open access: yes, 2011
本发明公开了一种常压无溶剂条件下双氧水直接氧化氯丙烯制环氧氯丙烷连续化的生产装置。由两台串联连续反应器与两台可切换并联的间歇反应器组成,该装置可以满足反应控制相转移催化剂催化氯丙烯环氧化反应特点,在连续反应器中进行均相催化环氧化,在间歇反应器中使环氧化进行完全,催化剂失去活性氧从反应体系析出,通过两台间歇反应器的切换实现反应控制相转移催化氯丙烯环氧化制环氧氯丙烷连续化生产过程。该装置操作简便,能耗和生产成本低,环境友好,可用于氯丙烯环氧化制备环氧氯丙烷中试实验或工业生产 ...
李军   +5 more
core   +4 more sources

Pre‐Established Zincophilic Na2SiO3 Decorated Array‐Like Channels to Regulate the Zn2+ Flux and Interfacial Corrosion for Dendrite‐Free Zinc Anode

open access: yesRare Metals, Volume 45, Issue 6, June 2026.
ABSTRACT Aqueous zinc‐ion batteries (AZIBs) have attracted increasing attention in energy storage owing to their high energy density, low redox potential, and cost‐effectiveness. Nevertheless, uncontrolled dendrite accumulation, gas generation, and severe side‐reaction problems hinder the cycling lifespan, which prevents their commercial applications ...
Xiangzhong Kong   +8 more
wiley   +1 more source

无溶剂条件下双氧水直接氧化氯丙烯制环氧氯丙烷连续化项目 [PDF]

open access: yes, 2011
无溶剂条件下双氧水直接氧化氯丙烯制环氧氯丙烷连续化项目待填
高爽
core  

Designing Additive‐Manufactured High‐Performance CoCrNi Matrix Composites Based on Grain Boundary Segregation

open access: yesRare Metals, Volume 45, Issue 6, June 2026.
ABSTRACT Through grain boundary segregation engineering, a crack‐free high‐strength CoCrNi medium‐entropy alloy (MEA) can be successfully fabricated via laser powder bed fusion (PBF‐LB). The influence of micron‐sized TiC particles on microstructural evolution, grain boundary segregation behavior, and mechanical properties was systematically ...
Cunliang Pan   +9 more
wiley   +1 more source

化學結構與溶解度對電化學氧化處理染料廢水的影響 [PDF]

open access: yes, 2014
本研究探討以電氧化法降解染料之溶液的效果,進而比較不同染料之化學結構(Azo,Diazo,Anthraquinone)與溶解度(Water Solubility),再以降解的難易程度對染料進行區分。實驗分別以電氧化直接法和間接法二種方式進行:直接法是使染料溶液與電解質混合直接電解;間接法則是直接電解電解質產生氧化劑,再將所產生之氧化劑溶液與染料溶液混合反應。處理後再分別量測直接法與間接法於不同操作參數下,染料溶液之色度與COD之氧化裂解反應,並透過色度與COD之降解程度 ...
陳俊成; 鄧文俊, 陳俊成
core   +1 more source

Interfacial Reconstruction of Li+ Solvation Shell for Fast Diffusion Kinetics in Low‐Temperature Dendrite‐Free Li Metal Battery Enabled by Atomic Catalysts

open access: yesRare Metals, Volume 45, Issue 6, June 2026.
ABSTRACT Low‐temperature lithium‐metal batteries (LT‐LMBs) are increasingly pursued for higher energy density and extended cycle life, yet suffer from severely depressed interfacial Li+ desolvation/diffusion kinetics due to the enlarged solvation structures as well as organic electrolyte solidification, ultimately inducing much higher barriers to ...
Shikai Yin   +14 more
wiley   +1 more source

染料污染物的有氧催化氧化降解研究 [PDF]

open access: yes, 2008
本论文发展了一个便宜、高效、环境友好的催化剂-FeCl3/NaNO2,它能在温和的条件下有效地活化分子氧来氧化降解一系列染料污染物。 发展了以FeCl3/NaNO2为催化剂的催化湿式氧化降解染料新体系。分别以蒽醌染料酸性蓝129 (AB129) 和偶氮染料酸性橙7 (AO7)为模型污染物,系统地考察了温度、催化剂各组分用量、氧气压力、溶液的初始pH值等因素对染料氧化降解的影响。在优化条件下,反应2小时AB129的脱色率为100%,同时TOC去除率为50.9%;反应4小时后硫的矿化率达到92 ...
彭艳蓉
core  

A Dual Co‐Reactant Accelerator Based On Nanoreactor‐Encapsulated CeO2 Nanozymes to Drive Potentiated Luminol Cathodic Electrochemiluminescence for Ultrasensitive Immunoassay

open access: yesRare Metals, Volume 45, Issue 5, May 2026.
ABSTRACT The precise quantification of cytokines is crucial for monitoring disease onset and progression. Herein, we developed a synergistic signal amplification approach by utilizing nanoreactor‐encapsulated CeO2 nanozymes, which were in situ electrodeposited within the mesoporous silica nanochannel film (SNF) grown on indium tin oxide (ITO ...
Yu Cui   +4 more
wiley   +1 more source

氯氧化铋在盐酸溶液中溶解度的测定和关联 [PDF]

open access: yes, 2014
在水解法制备氯氧化铋的反应结晶过程中,氯氧化铋在盐酸溶液中的溶解度数据至关重要。采用平衡法测定了303.15~363.15 K范围内氯氧化铋在盐酸溶液中的溶解度,并用Apelblat方程、经验多项式方程、λh方程对实验数据进行关联。结果表明:氯氧化铋溶解度随着盐酸浓度和温度的升高而增加,盐酸的浓度对氯氧化铋溶解度的影响更为显著;上述3种模型都可用于关联氯氧化铋的溶解度与温度的关系,就BiCl3-HCl-H2O体系而言,Apelblat方程、经验多项式方程和&lambda ...
张笛   +5 more
core  

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