碳电弧放电法是合成富勒烯及其衍生物的最重要方法之一,但电弧反应过程复杂,涉及的衍生化机制尚不明确.采用电弧法合成含有氯化富勒烯的碳灰,借助高效液相色谱法对其进行分离、纯化,得到了符合独立五元环规则的氯化富勒烯#24106C78Cl6,结合X-射线单晶衍射、质谱、紫外-可见吸收光谱对其进行结构表征,证明#24106C78Cl6与已有的氯化物#24106C78Cl18、#24106C78Cl30在六并苯片段具有相同的氯原子加成[5,6,6]位点,同时也证明了在氯参与的碳电弧中 ...
郑兰荪 +8 more
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Cao W, Wu Z, Zhao Y, Tong B, Yao K.
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Shi H +8 more
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Li D, Zhang Y, Chen Z, Chang W, Ding H.
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