, 2001 研究了2－氯－4－硝基－α，α，α-三氟甲氧基苯（CNTFMB）的氟化反应，考察了溶剂，相转移催化剂聚乙二醇（PEG6000），KF用量等因素对反应的影响。经实验确定了反应的最佳工艺条件为：n(CNTFMB):n(KF)=1.0:1.4，CNTFMB的质量（g）与溶剂DMF的体积（mL)之比为1：3，n(PEG6000):n(CNTFMB)=0.5:100.0，反应温度135℃，在此条件下，2－氟－4－硝基－α，α，α－三氟甲氧基苯（FNTFMB）的收率为85％，产品纯度w(FNTFMB)=95%
徐杰, 陈其亮
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