Results 1 to 10 of about 62,379 (92)

柠檬酸螯合Fe(Ⅲ)活化过硫酸盐降解活性艳红X-3B

open access: yesGongye shui chuli, 2018
文章研究了柠檬酸螯合Fe(Ⅲ)活化过硫酸盐体系对水中活性艳红X-3B的降解效果。考察了过硫酸盐浓度、Fe(Ⅲ)/柠檬酸(CA)、pH及阴离子(NO3-、NO2-、HCO3-、Cl-)对X-3B降解效果的影响,并研究体系中产生自由基的贡献率。结果表明,过硫酸盐浓度为0.2 mmol/L时,X-3B降解率最大;X-3B的降解率随Fe(Ⅲ)/CA增大而增大;pH的增大不利于X-3B的降解;无机阴离子的加入抑制X-3B的降解。·OH和SO4 ·-在光解过程中的贡献率分别为58%和31%。
张楠, 李建民, 汪应灵
doaj   +2 more sources

CuO-H2O2非均相催化氧化染料废水

open access: yesGongye shui chuli, 2013
以活性艳红X-3B为模拟底物,研究了低温常压条件下CuO-H2O2体系催化氧化染料废水的各种影响因素及反应机制。结果表明,CuO-H2O2体系能高效彻底地氧化活性艳红X-3B,氧化率可高达99%。CuO-H2O2体系降解染料废水的速率随温度、氧化剂和催化剂投加量以及X-3B废水初始浓度的升高而升高。酸性条件能促进X-3B废水的降解。与直接染料相比,CuO-H2O2体系降解活性染料废水更加有效。
周凌云, 郭伟
doaj   +2 more sources

絮状腐殖酸对废水中活性艳红的吸附研究

open access: yesGongye shui chuli, 2011
选用絮状腐殖酸作为吸附剂脱除废水中的活性艳红X-3B。研究了絮状腐殖酸对废水中活性艳红X-3B的吸附动力学、等温吸附模式以及pH、腐殖酸投加量对吸附效果的影响。结果表明,其吸附动力学符合准二级速率方程;吸附等温式满足Langmuir方程,最大单分子层吸附量为526.32 mg/g;废水中染料的去除率随溶液pH的减小而增加,随腐殖酸投加量的增加而增加。说明絮状腐殖酸可以作为一种廉价吸附材料,用于处理含染料废水。
许端平, 徐雪松, 褚海艳, 石萍
doaj   +2 more sources

Dimensional Assembly Engineering of Ce‐MOF Interfaces for Selective Recognition of Phytic Acid

open access: yesRare Metals, Volume 45, Issue 5, May 2026.
ABSTRACT Selective molecular recognition is central to chemical sensing yet discriminating structurally similar molecules at complex interfaces remains challenging. Traditional strategies based on tuning size, charge, or binding‐site chemistry often suffer from limited flexibility.
Qiang Miao   +7 more
wiley   +1 more source

Biomass‐Engineered Defect‐Rich g‐C3N4 Anchors Pd2+‐Rich Ultrafine Particles for Highly Efficient Formic Acid Dehydrogenation

open access: yesRare Metals, Volume 45, Issue 4, April 2026.
ABSTRACT Formic acid (FA) is considered to be a safe and convenient hydrogen source; however, achieving controlled and efficient FA dehydrogenation under mild conditions using stable solid catalysts remains a significant challenge. Pd‐based catalysts have been extensively studied due to their superior catalytic activity to other metal catalysts.
Shuai Wei   +10 more
wiley   +1 more source

An Ultrasmall Strontium‐Loaded Polydopamine Nanoformulation for Near‐Infrared‐Enhanced Periodontitis Therapy via Photodynamic Gas‐Promoted Antibacterial and Bone Repair

open access: yesRare Metals, Volume 45, Issue 3, March 2026.
ABSTRACT Periodontitis is a chronic infectious oral disease triggered by periodontopathogenic bacteria, resulting in the progressive inflammation and destruction of the tissues surrounding teeth. To achieve reprogramming of the infectious microenvironment for periodontitis therapy, a nanoformulation was proposed by loading polydopamine (PDA) with ...
Hao Liang   +14 more
wiley   +1 more source

Amphiphilic Block Copolymer‐Functionalized VO2 Nanocomposites for Smart Waterborne Polyurethane Coatings

open access: yesRare Metals, Volume 45, Issue 3, March 2026.
ABSTRACT Aqueous vanadium dioxide (VO2)‐based smart thermal insulation coatings represent a viable strategy to decrease building energy consumption and advance sustainable development goals. However, the inherent instability and limited compatibility with polymer matrices of VO2 hinder its widespread application.
Xiuxian Zhao   +9 more
wiley   +1 more source

NIR‐Responsive Nano‐Integrated Magnesium Phosphate Cement Promotes Bone Regeneration via Osteoblast‐Exosome‐Osteoclast Crosstalk

open access: yesRare Metals, Volume 45, Issue 2, February 2026.
ABSTRACT The limited osteogenic capacity of magnesium phosphate cement (MPC) has constrained its biomedical applications, underscoring the necessity to develop MPC with enhanced physical properties and bone‐forming capabilities. In this study, a multifunctional MPC system was developed by incorporating zoledronic acid‐loaded near‐infrared (NIR ...
Bin Wang   +8 more
wiley   +1 more source

Fabricating Highly Efficient Ternary Mn–CeOx/Co3O4 Catalysts for Low Temperature Thermal Desorption of Persistent Perfluorooctanoic Acid in Soil

open access: yesRare Metals, Volume 45, Issue 1, January 2026.
ABSTRACT Developing efficient catalytic thermal desorption systems is of great significance in the field of sustainable soil remediation. Herein, novel Mn–Ce solid solution modified Co3O4 nanocrystals were successfully prepared for the removal of perfluorooctanoic acid (PFOA) in soil.
Yu‐Hao Liu   +8 more
wiley   +1 more source

花椒内生真菌高效脱色酸性红X-3B及固定化菌剂构建

open access: yesGongye shui chuli
印染废水中的偶氮染料酸性红X-3B难以降解,对环境造成严重污染。为寻求高效生物处理途径,本研究从陇南花椒叶片中筛选获得一株高效脱色菌株HJ,经形态学与分子生物学鉴定为烟管菌属白腐菌(Bjerkandera ecuadorensis)。系统研究了pH、染料质量浓度、碳氮源、金属离子及装液量等因素对其脱色性能的影响,并利用液相色谱-质谱联用(LC-MS)分析降解产物,初步阐明其降解机制。进一步采用海藻酸钠-氯化钙包埋法制备固定化真菌微球,并评估其脱色效率与稳定性。结果表明:在pH 5.0、染料质量浓度50 ...
田凤鸣   +8 more
doaj   +4 more sources

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