An Improved Synthetic Method for Sensitive Iodine Containing Tricyclic Flavonoids [PDF]
Molecules, 2022 The synthesis of new iodine containing synthetic tricyclic flavonoids is reported. Due to the sensitivity of the precursors to the heat and acidic conditions required for the ring closure of the 1,3-dithiolium core, a new cyclization method has been ...
Mihail Lucian Birsa, Laura G. Sarbu
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An Approach to Paracyclophane-Based Tetrathiafulvalenes: Synthesis and Characterization of a Pseudo-Geminal [2.2]Paracyclophane 1,3-Dithia-2-Thione [PDF]
Molecules, 2020 The synthesis of paracyclophane-based tetrathiafulvalene precursors is described in the context of the importance of these compounds in the field of material chemistry.
Lucian G. Bahrin +4 more
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[2.2]Paracyclophane derivatives containing tetrathiafulvalene moieties [PDF]
Beilstein Journal of Organic Chemistry, 2015 The synthesis of [2.2]paracyclophane derivatives containing tetrathiafulvalene units has been accomplished by the coupling reaction of 4-([2.2]paracyclophan-4-yl)-1,3-dithiol-2-thione in the presence of trimethylphosphite.
Laura G. Sarbu +4 more
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Synthesis of Thieno[2,3-d]-1,3-dithiol-2-thiones from Thieno[2,3-d]-1,2,3-thiadiazoles: Matryoshka-type autoclave for high-temperature, high-pressure thermolysis microscale reactions [PDF]
Molecules, 2002 Thieno[2,3-d]-1,2,3-thiadiazoles (1) react with carbon disulfide in a "Matryoshkatype" double compartment autoclave [1] to yield thieno[2,3-d]-1,3-dithiol-2-thiones (2).
Ving J. Lee +3 more
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Tetrathiafulvalene - a redox-switchable building block to control motion in mechanically interlocked molecules. [PDF]
Beilstein J Org Chem, 2018 With the rise of artificial molecular machines, control of motion on the nanoscale has become a major contemporary research challenge. Tetrathiafulvalenes (TTFs) are one of the most versatile and widely used molecular redox switches to generate and ...
Schröder HV, Schalley CA.
europepmc +3 more sources
Reaction of 1,4,2-Dithiazolium and 1,3-Dithiolium Salts with Malononitrile [PDF]
Bulletin of the Chemical Society of Japan, 1989 Abstract The reaction of 5-substituted 3-phenyl-1,4,2-dithiazolium salts with malononitrile gave not only 5-dicyanomethylene-3-phenyl-1,4,2-dithiazole and an isothiazole derivative, but 4-amino-5-cyano-2-(1-cyano-2-dialkylamino-2-mercaptovinyl)-6-phenylpyrimidines (6) and a butadiene derivative, depending on substituents at C-5 and bases
Katsumi Yonemoto +2 more
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Iminium Salts of ω-Dithiafulvenylpolyenals: An Easy Entry to the Corresponding Aldehydes and Doubly Proaromatic Nonlinear Optic-phores [PDF]
, 2008 A short, high-yielding route to ω-dithiafulvenylpolyenals (1) via the corresponding iminium salts (2) and starting from trimethyl-1,3-dithiolium tetrafluoroborate is reported.
B. Villacampa +11 more
core +2 more sources
Tris(pentafluorophenyl)borane and beyond: modern advances in borylation chemistry [PDF]
, 2017 As main-group chemistry, in particular boron chemistry, has expanded and developed over the past 20 years, one reagent has risen to prominence as well.
James R. Lawson +3 more
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A binaphthol-substituted tetrathiafulvalene with axial chirality and its enantiopure TCNQF4 charge-transfer salts [PDF]
, 2011 International audienceA chiral tetrathiafulvalene (1) bearing a binaphtholdimethylene moiety on one side, an ethylenedithio substituent on the other side, is prepared from atropoisomeric (R)-, (S)- and racemic (R,S)-binaphthol. Its oxidation potential (0.
Fourmigué, Marc +2 more
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Novel 9,10-bis(1,3-dithiol-2-ylidene)-9,10-dihydroanthracene derivatives bridged by a crown ether unit at the 1,8-positions: A new type of redox-switchable hosts undergoing reversible structural changes [PDF]
, 2006 Novel redox-switchable host molecules (2) composed of a 9,10-bis(1,3-dithiol-2-ylidene)-9,10-dihydroanthracene unit and a crown ether moiety bridging the 1,8-positions have been synthesized.
Fujimori, K +3 more
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