Tetrathiafulvalene - a redox-switchable building block to control motion in mechanically interlocked molecules. [PDF]
With the rise of artificial molecular machines, control of motion on the nanoscale has become a major contemporary research challenge. Tetrathiafulvalenes (TTFs) are one of the most versatile and widely used molecular redox switches to generate and ...
Schröder HV, Schalley CA.
europepmc +3 more sources
X-Ray Crystallographic Data on Certain Substituted 1,2- and 1,3-Dithiolium Salts, and two Substituted 1,2-Dithioles. [PDF]
Asbjørn Hordvik +4 more
openaire +2 more sources
Iminium Salts of ω-Dithiafulvenylpolyenals: An Easy Entry to the Corresponding Aldehydes and Doubly Proaromatic Nonlinear Optic-phores [PDF]
A short, high-yielding route to ω-dithiafulvenylpolyenals (1) via the corresponding iminium salts (2) and starting from trimethyl-1,3-dithiolium tetrafluoroborate is reported.
B. Villacampa +11 more
core +2 more sources
Tris(pentafluorophenyl)borane and beyond: modern advances in borylation chemistry [PDF]
As main-group chemistry, in particular boron chemistry, has expanded and developed over the past 20 years, one reagent has risen to prominence as well.
James R. Lawson +3 more
core +2 more sources
Novel 9,10-bis(1,3-dithiol-2-ylidene)-9,10-dihydroanthracene derivatives bridged by a crown ether unit at the 1,8-positions: A new type of redox-switchable hosts undergoing reversible structural changes [PDF]
Novel redox-switchable host molecules (2) composed of a 9,10-bis(1,3-dithiol-2-ylidene)-9,10-dihydroanthracene unit and a crown ether moiety bridging the 1,8-positions have been synthesized.
Fujimori, K +3 more
core +3 more sources
A binaphthol-substituted tetrathiafulvalene with axial chirality and its enantiopure TCNQF4 charge-transfer salts [PDF]
International audienceA chiral tetrathiafulvalene (1) bearing a binaphtholdimethylene moiety on one side, an ethylenedithio substituent on the other side, is prepared from atropoisomeric (R)-, (S)- and racemic (R,S)-binaphthol. Its oxidation potential (0.
Fourmigué, Marc +2 more
core +3 more sources
Functionalised tetrathiafulvalene- (TTF-) macrocycles: recent trends in applied supramolecular chemistry [PDF]
Tetrathiafulvalene (TTF) has been extensively explored as a π-electron donor in supramolecular systems. Over the last two decades substantial advances have been made in terms of constructing elaborate architectures based on TTF and in exploiting the ...
A. Jana +7 more
core +1 more source
Metallkomplexe mit biologisch wichtigen Liganden, LXV [PDF]
Cp*Co(CO)I2 (Cp* = 5-C5Me5), [(6-arene)RuCl2]2 (arene = p-cymene, hexamethylbenzene), and [Cp*MCl2]2 (M = Rh, Ir) react with -amino amides and various peptide esters to give the N,O-chelate complexes [Cp*(I)Co - NH2C(H)(R1)C(NHR2)-O]+ (1), [(6-arene ...
Beck +32 more
core +1 more source
Glycine Residue Twists HOMO¿HOMO Interactions in a Molecular Conductor [PDF]
We report on radical cation salts of EDT-TTF cores bearing a glycine residue with hydrogenosulfate, [HSO4−], or the amphoteric para- carboxybenzenesulfonate, [HO2C-C6H4-SO3−].
Alemany i Cahner, Pere +7 more
core +1 more source
Studies in the dithiole series [PDF]
Using previously developed methods, several new dithiolium salts have been prepared, and others have been synthesised by modification of Known methods. 3-Benzyl-5-phenyl-I,2-ditniolium perchlorate has been prepared by reaction of benzoylphenylacetone
McKinnon, David Mackie
core

