Results 131 to 140 of about 21,256,998 (238)
ABSTRACT Nanostructured titanium (Ti) facilitates osteoblast differentiation by modulating various signaling pathways and may enhance osseointegration, potentially through its influence on the formation and remodeling of the extracellular matrix (ECM). This study aimed to investigate the impact of osteoblast‐ECM‐functionalized nanostructured Ti surface
Georgia Kors Quiles +7 more
wiley +1 more source
Photochromic carbazole photoinitiators for precision visible‐light photopolymerization
New carbazole–naphthopyran derivatives were employed as visible‐light‐activated photoinitiators, enabling rapid and localized radical photopolymerization to produce well‐defined thin solid objects within minutes. Abstract Two carbazole derivatives, each incorporating a naphthopyran unit and an aromatic ketone, were synthesized and evaluated as ...
Mauro Magalhães +3 more
wiley +1 more source
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley +1 more source
Synthesis of Benzopyran Atropisomers via Electrophilic Halogenation
We report a halogenation‐based method for the synthesis of axially chiral benzopyrans, tolerating diverse substituents and halogens (Br, Cl, and I). A double bromination gives bisbenzopyrans with two stereogenic axes. Preliminary enantioselective conditions yield benzopyran atropisomer with up to 56% ee.
Alix Bourhis +3 more
wiley +1 more source
Polysilane‐Supported Nickel as an Efficient Catalyst for the Hydrogenation of Aromatic Compounds†
A Ni/Si catalyst obtained from the reaction of poly(monohydro)silane with Ni(cod)2 serves as an effective heterogeneous catalyst for the hydrogenation of arenes under reaction conditions that are significantly milder than those required for conventional nickel‐based catalysts such as Raney nickel.
Hiromu Baba, Yusuke Sunada
wiley +1 more source
Aminoferrocene‐based prodrugs represent a promising class of redox‐active anticancer agents that can be selectively activated in oxidative cellular environments. However, activation of these systems typically relies on reactive oxygen species (ROS) and is therefore inefficient in intracellular compartments with low ROS levels, such as the cytoplasm. In
Hülya Gizem Özkan +5 more
wiley +1 more source
Experimental and Computational Elucidation of Protic Redox Reaction Mechanisms
Comparing quantum chemical calculations of redox potentials against experimental data provides a powerful and cost‐effective method for validating proposed protic redox reaction mechanisms, provided that computational and experimental uncertainties are robustly quantified. Molecular design of redox‐active species for applications such as redox sensing,
Lachlan O. Smith, Deborah L. Crittenden
wiley +1 more source
Intermolecular Asymmetric Arylative Dearomatization of 1-Naphthols
Arylative dearomatization forms quaternary stereocenters in cyclic systems with the concomitant introduction of an aromatic ring. Pd-catalyzed arylative dearomatization, which uses conditions analogous to cross-coupling, has emerged as a powerful method in an intramolecular context.
Kadarauch, Max +2 more
openaire +3 more sources
The herein‐developed tyrosinase model complex enables the transfer of tyrosinase‐like catalytic oxygenation activity into artificial systems. Therefore, it enables the use of molecular oxygen for oxygenation and oxidation of phenolic substrates at room temperature.
Rosalie Dalhoff +3 more
wiley +1 more source
Carga superficial de agregados nanoestruturados [PDF]
Tese (doutorado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas. Programa de Pós-Graduação em Química.A adição de sais em soluções de surfactantes dipolares iônicos promove incorporação específica de ânions nas ...
Silva, Marcelo
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