Results 111 to 120 of about 149,407 (284)

Mini‐Hairpin DNA: Extraordinarily Stable Structure and Its Applications

open access: yesChemistry – A European Journal, EarlyView.
Mini‐hairpin DNA fragments containing GCGAAGC and GCGAAAGC form exceptionally stable hairpin‐like structures, with only two G−C pairs and one sheared G−A pair, remaining undenatured in 7 M urea and resisting nuclease digestion. These mini‐hairpin sequences frequently appear in replication and transcription origins, influence DNA sequencing fidelity ...
Michiko Kimoto, Ichiro Hirao
wiley   +1 more source

Recuperação de 15N-ureia no sistema solo-planta de pastagem de capim-tanzânia Recovery of 15N-urea in soil-plant system of tanzania grass pasture

open access: yesRevista Brasileira de Ciência do Solo, 2009
O atrativo econômico e o impacto ambiental da adubação nitrogenada em pastagens dependem da eficiência de uso do nitrogênio (N) do fertilizante no sistema solo-planta. Entretanto, a recuperação do 15N-ureia em pastagem de Panicum maximum cv.
Geraldo Bueno Martha Júnior   +3 more
doaj   +1 more source

Linear and Two‐Dimensional Infrared Spectroscopy of the Multifunctional Vibrational Probe, 3‐(4‐Azidophenyl) Propiolonitrile. Deperturbing a Fermi Triad by Isotopic Substitution

open access: yesChemPhysChem, Volume 26, Issue 6, March 15, 2025.
Linear infrared spectroscopy combined with isotope labeling and density functional theory unravels the origin of a Fermi triad in a multifunctional vibrational chromophore. Ultrafast 2DIR‐spectroscopy reports directly on the dynamics and the intramolecular vibrational energy flow pathways in the isotopically deperturbed system. Abstract Infrared probes
Claudia Gräve   +4 more
wiley   +1 more source

Mesure de la digestibilité des protéines par la méthode des différences porto-artérielles chez l’espèce porcine

open access: yesOléagineux, Corps gras, Lipides, 2003
This paper gives an overview of the current in vivo methods used to evaluate nutritional quality of proteins. It present in the first part methods used to assess digestibility of proteins, the interest and constraints of portal measurements and finally ...
Rychen Guido
doaj   +1 more source

Optimal control of fast and high-fidelity quantum gates with electron and nuclear spins of a nitrogen-vacancy center in diamond

open access: yes, 2015
A negatively charged nitrogen vacancy (NV) center in diamond has been recognized as a good solid-state qubit. A system consisting of the electronic spin of the NV center and hyperfine-coupled nitrogen and additionally nearby carbon nuclear spins can form
Chou, Yi   +2 more
core   +1 more source

Mononuclear Molybdenum and Tungsten Phosphine Complexes for Catalytic Ammonia Synthesis: Development of the pentaPod Concept

open access: yesChemPhysChem, EarlyView.
The pentaPod (P5) concept unites tridentate and tripodal fragments to form molybdenum and tungsten catalytic Chatt‐type complexes for N2‐to‐NH3 reduction. Two pentaPod ligands, P5Me and P5Pln, are available with either two dimethylphosphine or phospholano (Pln) groups. The complexes enable the investigation of reactivity differences in N2 reduction and,
Anna‐Marlene Vogt   +3 more
wiley   +1 more source

Impacts of large herbivores on mycorrhizal fungal communities across the Arctic

open access: yesEcography, EarlyView.
Mycorrhizal fungi play an integral role in nutrient and carbon cycling in soils, which may be especially important in the Arctic, one of the world's most soil carbon‐rich regions. Large mammalian herbivores can influence these fungi through their impacts on vegetation and soil conditions, however the strength and prevalence of these interactions in the
Cole G. Brachmann   +25 more
wiley   +1 more source

Dinuclear Rhodium(I)–N‐Heterocyclic Carbene Complexes as Alkyne Hydropyridonation Catalysts

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
Catalyst Improvement by NHC tuning: A series of new RhI–NHC dinuclear complexes has been revealed as efficient alkyne hydropyridonation catalysts. 333053IMes complex displays the highest reactivity of the series, suggesting that a moderate steric demand combined with balanced σ‐donation facilitates precatalyst activation and substrate exchange.
Belinda Español‐Sánchez   +7 more
wiley   +1 more source

Syntheses of 15N-labeled pre-queuosine nucleobase derivatives

open access: yesBeilstein Journal of Organic Chemistry, 2014
Pre-queuosine or queuine (preQ1) is a guanine derivative that is involved in the biosynthetic pathway of the hypermodified tRNA nucleoside queuosine (Que). The core structure of preQ1 is represented by 7-(aminomethyl)-7-deazaguanine (preQ1 base).
Jasmin Levic, Ronald Micura
doaj   +1 more source

Guidelines for Sample Preparation and Stable Isotope Analysis of Food for Traceability Studies

open access: yesFood Safety and Health, EarlyView.
This workflow illustrates sample preparation and analysis steps in stable isotope ratio mass spectrometer (IRMS) for food traceability. It emphasizes standardized preparation, encapsulation, calibration, and quality control to ensure accurate, comparable isotope data critical for verifying food origin and authenticity across complex supply chains ...
Bayan Nuralykyzy   +8 more
wiley   +1 more source

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