Results 41 to 50 of about 68,942 (307)

Models for incomplete nucleophilic attack on a protonated carbonyl group and electron-deficient alkenes : salts and zwitterions from 1-dimethylamino-naphthalene-8-carbaldehyde [PDF]

, 2012
The X-ray crystal structures of salts and zwitterionic Knoevenagel products from 1-dimethylamino-naphthalene-8-carbaldehyde show long N–C bonds between peri-groups which provide models for incomplete nucleophilic attack on a protonated carbonyl group and
Rees, GJ, Pitak, MB, Pitak, Matuesz B., Day, SP, Smith, Mark E., Smith, M.E., Coles, Simon J., Rees, Gregory J., Rees, Gethin, Hanna, John V., Smith, ME, Lari, Alberth, Wallis, J.D., Day, Stephen P., Coles, SJ, Lari, A, Hanna, JV, Pitak, Mateusz, Day, Stephen Paul, Day, S.P., Wallis, JD, Wallis, John D., Hanna, J.V.   +22 more
core   +1 more source

Magnetic‐Field Control of Surface States in CoFe2O4 Thin Films for Nitrate Electroreduction to Ammonia

Advanced Functional Materials, EarlyView.
Magnetic‐field‐assisted CVD of heterometallic single‐source precursors modulates thin‐film surface electronic structure and interfacial charge transfer. Field‐grown (Cobalt ferrite‐1T)CF‐1T films exhibit stabilized electronic states, lower kinetic barriers, and markedly enhanced nitrate‐to‐ammonia electrocatalysis versus (Cobalt ferrite‐0T) CF‐0T ...
Touraj Karimpour, Younes Mousazade, Simon Diel, Shilendra Kumar Sharma, Tisita Das, Nathália C. Verissimo, Thomas Fischer, Ziyaad Aytuna, Andreas Lichtenberg, Sudip Chakraborty, Marcel Risch, Sanjay Mathur   +11 more
wiley   +1 more source

Exogenous GA3 alleviates low nitrogen stress by enhancing leaf nitrogen assimilation and limiting the transport of photosynthates to roots in apple plants

Fruit Research
Gibberellins (GAs) are crucial for improving plant adaptation to abiotic stresses; however, their physiological functions in apple plants under low-nitrogen (N) stress remain unclear. In this work, a hydroponic approach was used to explore the effects of
Jingquan Liu, Mengxue Lyu, Chunling Liu, Wei Ni, Yafei Guan, Hongmei Xie, Yue Xing, Ziquan Feng, Zhanling Zhu, Shunfeng Ge, Yuanmao Jiang   +10 more
doaj   +1 more source

General Synthesis of Amorphous Pd‐Based Nanoparticles Towards Highly Efficient Nitrate‐to‐Ammonia Electrocatalysis

Advanced Functional Materials, EarlyView.
A family of amorphous palladium‐based multi‐component phosphides nanoparticles, synthesized via a robust one‐step wet‐chemical method, overcoming the immiscibility of different elements and the difficulty in forming a stable, disordered structure. When applied in the electrochemical nitrate reduction reaction, these nanocatalysts effectively suppress ...
Lei Xu, Chuhao Luan, Mingzi Sun, Weiwei Chen, Xiaozhi Liu, Chen Ma, Long Zheng, Gang Wang, Peng Han, Ping Gu, Xiao Wang, Chenhao Shu, Cheng Lyu, Zhenyu Zhang, Nailiang Yang, Hongyan He, Xiaohong Li, Dong Su, Bolong Huang, Wenjun Zhang, Ye Chen   +20 more
wiley   +1 more source

New Water Oxidation Mechanism in Photosystem II Resolves Major Experimental Controversies

Angewandte Chemie, EarlyView.
In Photosystem II Oxygen Evolving Complex, we discovered the O3‐O6 peroxide at lower energy. Assignment of the O3 ligated by histidine (His337) as a slow exchanging substrate and its coupling with O6 give the O─O bond formation mechanism most consistent with all currently available experimental data. Proposal shows how protein environment can steer the
Yulia Pushkar
wiley   +2 more sources

In Situ Amine Formation to Modulate MOF‐Derived PdIn N‐Doped Carbon Catalysts

Advanced Materials, EarlyView.
An amine‐assisted approach converts PdIn‐MOF into PdIn intermetallic nanoparticles embedded in N‐doped carbon. In situ‐generated amines trigger early Pd nucleation, producing smaller PdIn domains than direct pyrolysis. Amine sterics and basicity tune composition and particle size, while solvent and amine co‐determine textural features.
Gonzalo Egea, Jordan Santiago Martinez, M. Asunción Molina, Jaime Mazarío, Lucy Costley‐Wood, Christian Cerezo‐Navarrete, Carlo Marini, Eduardo Villalobos‐Portillo, Andrew M. Beale, Pascual Oña‐Burgos   +9 more
wiley   +1 more source

Water‐Mediated Phosphoryl Wires Stabilize Pathological Tau Fibrils

Angewandte Chemie, EarlyView.
Extended 1D phosphoryl “wires” stabilize in‐register amyloid tau fibrils, as demonstrated by multiple‐quantum spin‐counting NMR, TEM, and MD simulations, using fibrils of tau peptide jR2R3‐P301L (tau295–313) with phosphorylation at S305 or Y310. ABSTRACT Hyperphosphorylation of tau is a hallmark of tauopathies, with specific phosphorylation sites ...
Lokeswara Rao Potnuru, Austin DuBose, Fiona Mon, Mesopotamia S. Nowotarski, Michael Vigers, Boqin Zhang, Chung‐Ta Han, John E. Straub, Songi Han   +8 more
wiley   +2 more sources

15N-1H ZZ exchange: 15N BMAL1 TAD at 65C

, 2017
Each .ft file represents a different time delay in the ZZ exchange assay, with specific delay information included in the times. txt file.
Carrie Partch (6999542), Chelsea Gustafson (6999545)   +1 more
core   +1 more source

QBP1 Peptide as a Potential Anti‐Amyloidogenic Therapy for Type 2 Diabetes: An In Vitro Study

Advanced Science, EarlyView.
The anti‐amyloidogenic peptide QBP1 effectively halts human islet amyloid polypeptide (hIAPP) aggregation, preventing the formation of toxic β‐structured intermediates. Through a combination of biophysical assays, molecular dynamics, and cell‐based studies, QBP1 is shown to preserve β‐cell viability and metabolic homeostasis, positioning it as a ...
María M. Tejero‐Ojeda, Ada Bernaus Vives, Michał Wojciechowski, Dinh Quoc Huy Pham, Mateusz Chwastyk, Mario Vallejo, Anna Novials, Douglas V. Laurents, Mariano Carrión‐Vázquez   +8 more
wiley   +1 more source

Palladium‐Doping‐Enabled Interface Synergy for Superb Ampere Level Ammonia Electrosynthesis From Nitrate

Angewandte Chemie, EarlyView.
Isolated Pd sites in a metallic Co matrix boost nitrate‐to‐ammonia conversion. Pd doping optimizes intermediate adsorption and reconstructs the interfacial microenvironment, promoting cation enrichment and a hydrogen‐down‐oriented water network. This dual modulation facilitates proton transfer and intermediate stabilization, enabling high ammonia ...
Qun He, Chuanqiang Wu, Zhangsheng Shi, Dongxue Yu, Wei Jiang, Li Song, Xin Wang   +6 more
wiley   +2 more sources