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Bioerodible hydrogels based on 2‐hydroxyethyl methacrylate: Synthesis and characterization

Journal of Applied Polymer Science, 2002
AbstractBiocompatible polymers with specific shape and tailored hydrogel properties were obtained by polymerization of mixtures of 2‐hydroxyethyl methacrylate (HEMA) with 1–8 wt % ethylene glycol dimethacrylate (EGDMA) or tetra(ethylene glycol) diacrylate (TEGDA) as crosslinking agents, by using a redox initiator.
CHIELLINI, FEDERICA   +3 more
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Copolymerization of 2-hydroxyethyl methacrylate with alkyl acrylates

European Polymer Journal, 1976
Abstract Copolymerization of 2-hydroxyethyl methacrylate (HEMA) with methylacrylate (MA), ethylacrylate (EA), n -butylacrylate (BA) and methylmethacrylate (MMA) were studied in bulk at 60° using benzoyl peroxide as initiator. The monomer reactivity ratios were determined using several methods and are briefly discussed.
I.K. Varma, S. Patnaik
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Relaxation Behaviour of Poly(2-Hydroxyethyl Acrylate) and of Its Copolymers with 2-Hydroxyethyl Methacrylate

International Journal of Polymeric Materials, 1975
Abstract The molecular mobility of poly(2-hydroxyethyl acrylate) (PHEA) and of its copolymers with 2-hydroxyethyl methacrylate (H EM A) was determined by means of dynamic mechanical measurements with a torsional pendulum. The low-temperature dispersion assigned to the motion of the hydroxyethyl groups of the side chains was observed at -133°C (1 Hz ...
J. Kolařík, J. Vacík, J. Kopeček
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Copolymers of 2‐hydroxyethyl methacrylate and alkyl methacrylates. I. Synthesis and characterization

Journal of Polymer Science: Polymer Chemistry Edition, 1985
AbstractCopolymerization of 2‐hydroxyethyl methacrylate (HEMA) with ethyl methacrylate (EMA) and n‐butyl methacrylate (BMA) was carried out in bulk at 70°C ± 1°C using 0.2% benzoyl peroxide as initiator in nitrogen atmosphere. Number average molecular weight (Mn) of the copolymers was determined by dynamic osmometry. Intrinsic viscosity [η] of HEMA‐BMA
Manjeet S. Choudhary, Indra K. Varma
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Dynamic mechanical properties of polymer-fluid systems: characterization of poly(2-hydroxyethyl methacrylate) and poly(2-hydroxyethyl methacrylate-co-methyl methacrylate) hydrogels

Polymer, 1991
Abstract The complex shear moduli of crosslinked poly(2-hydroxyethyl methacrylate) and poly(2-hydroxyethyl methacrylate-co-methyl methacrylate) hydrogels were measured as a function of water content, temperature and frequency using dynamic mechanical spectroscopy.
Steven R. Lustig   +2 more
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Conformational analysis of poly(2‐hydroxyethyl methacrylate)

Journal of Polymer Science Part A: Polymer Chemistry, 1991
AbstractThe poly(2‐hydroxyethyl methacrylate) (PHEMA) is a disubstituted vinyl chain in which the substituents CO2CH2CH2OH and CH3 differ in size and shape. In order to verify the various characteristics of the PHEMA chain, the conformational energy calculations for meso and racemic diads, which are the segments consisting of the stereoregular ...
Jeong Hyeok Yoon   +3 more
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An ultrastructural study of the biocompatibility of poly(2‐hydroxyethyl methacrylate) in bone

Journal of Biomedical Materials Research, 1975
AbstractBecause of the unique properties for swelling in a fluid medium and variable modulus of elasticity, hydrophilic methacrylates may be of potential usefulness for implanting prosthetic devices in bone. To investigate the biocompatibility, electron micrographic studies were done on specimens of poly(2‐hydroxyethyl methacrylate) imbedded in bone ...
D G, Murray, J S, Dow
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Pressurized polymerization for reaction casting of poly(2‐hydroxyethyl methacrylate)

Journal of Biomedical Materials Research, 1981
AbstractHomopolymers of the hydrogel poly(2‐hydroxyethyl methacrylate) are produced with no observable bubbles trapped in the lattice by performing the free radical initiated polymerization reaction under pressure (700 kPa). Implantable hydrogel structures of intricate and exact geometry, such as nipples for ureteral anastomoses in the prosthetic ...
L, Pinchuk, E C, Eckstein
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Copolymerization of 2-Hydroxyethyl Methacrylate with Carboxylic Monomers

Polymer Science, Series D, 2019
The results of experimental studies on copolymerization kinetics of 2-hydroxyethyl methacrylate with carboxyl-containing monomers of acrylic, methacrylic, and maleic acids in water using the redox initiator system of ammonium persulfate–ascorbic acid are summarized.
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Immediate contact reaction to 2-hydroxyethyl methacrylate?

Contact dermatitis, 2000
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Devos, S.A., Valk, P.G.M. van der
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