Synthesis of Benzopyran Atropisomers via Electrophilic Halogenation
We report a halogenation‐based method for the synthesis of axially chiral benzopyrans, tolerating diverse substituents and halogens (Br, Cl, and I). A double bromination gives bisbenzopyrans with two stereogenic axes. Preliminary enantioselective conditions yield benzopyran atropisomer with up to 56% ee.
Alix Bourhis +3 more
wiley +1 more source
Polysilane‐Supported Nickel as an Efficient Catalyst for the Hydrogenation of Aromatic Compounds†
A Ni/Si catalyst obtained from the reaction of poly(monohydro)silane with Ni(cod)2 serves as an effective heterogeneous catalyst for the hydrogenation of arenes under reaction conditions that are significantly milder than those required for conventional nickel‐based catalysts such as Raney nickel.
Hiromu Baba, Yusuke Sunada
wiley +1 more source
Aminoferrocene‐based prodrugs represent a promising class of redox‐active anticancer agents that can be selectively activated in oxidative cellular environments. However, activation of these systems typically relies on reactive oxygen species (ROS) and is therefore inefficient in intracellular compartments with low ROS levels, such as the cytoplasm. In
Hülya Gizem Özkan +5 more
wiley +1 more source
An effective and environment-friendly protocol for the synthesis of indenonaphthapyranes has been developed by one-pot reaction of 2-naphthol; various aromatic aldehydes; and 1,3-indandione, in the presence of copper(II) triflate as catalyst, while using
Kadir Turhan +3 more
doaj
Bull. Chem. Soc. Ethiop. 1995, 9(1), 1-8.
Elizabeth Yohannes +2 more
doaj
New Microporous Lanthanide Organic Frameworks. Synthesis, Structure, Luminescence, Sorption, and Catalytic Acylation of 2-Naphthol. [PDF]
Bejan D +6 more
europepmc +1 more source
Base-Regulated Spiroannulation: Insights into the Palladium-Catalyzed [2 + 2 + 1] Annulation of 1,2-Dihaloarenes, Alkynes, and 2‑Naphthol. [PDF]
Zhong JF +7 more
europepmc +1 more source
ZnO Nanocatalyst-Enabled Microwave-Assisted Solvent-Free Synthesis of Functional Amidoalkyl-2-naphthol Derivatives: A Synergistic Experimental and Quantum Chemical Study. [PDF]
Daniel Aroquiaraj AR +7 more
europepmc +1 more source
Three-component reaction of formyl-substituted donor-acceptor cyclopropanes, primary aromatic amines and 2-naphthol: access to cyclopropane fused 2-pyrrolidinone derivatives. [PDF]
Devaraj T, Srinivasan K.
europepmc +1 more source
Simple and reliable method to simultaneously determine urinary 1- and 2-naphthol using in situ derivatization and gas chromatography-mass spectrometry for biological monitoring of naphthalene exposure in occupational health practice. [PDF]
Takeuchi A +10 more
europepmc +1 more source

