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Efficient Approaches to the Design of Six-Membered Polyazacyclic Compounds-Part 1: Aromatic Frameworks. [PDF]
Gyrgenova EA, Titova YY, Ivanov AV.
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Recent trends for chemoselectivity modulation in one-pot organic transformations. [PDF]
Chaudhary HR, Patel DM.
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2H-Azirines in Medicinal Chemistry
Chemistry of Heterocyclic Compounds, 2021The review presents an analysis of studies published in the period 1971–2020 devoted to examination of the biological activity of natural and synthetic 2H-azirine derivatives, their use for bioconjugation, as well as search for some new synthetic methods of structural modification of azirines with the aim of improving their biological activity.
Mikhail S. Novikov, Nikolai V Rostovskii
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2H-Azirines as Synthetic Tools in Organic Chemistry
European Journal of Organic Chemistry, 2001The versatility and the high synthetic potential including the asymmetric syntheses of 2H-azirines as valuable precursors for the preparation of a wide range of polyfunctional acyclic and cyclic compounds, is discussed.
Francisco Palacios +2 more
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Recent approaches to the synthesis of 2H-azirines
The most recent (2013–2018) synthetic approaches toward 2H-azirine derivatives are summarized and discussed. This minireview covers the latest examples on the synthesis of 2H-azirines that can be gathered in five distinct categories: the Neber approach, decomposition of vinyl azides, ring contraction of isoxazoles, oxidative cyclization of enamine ...
Ramkumar N. +3 more
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Synthesis and Reactivity of 2-Halo-2H-Azirines Towards Nucleophiles [PDF]
Nucleophilic substitution reactions of 2-halo-2H-azirine with potassium phthalimide and aniline allowed the preparation of new substituted 2H-azirines.
Teresa Pinho e Melo, Cláudia S J Lopes
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Enantioselective addition of organolithium reagents to a 2H-azirine
Tetrahedron: Asymmetry, 2002AbstractFor Abstract see ChemInform Abstract in Full Text.
Erik Risberg, Peter Somfai
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Tetrahedron, 1984
Abstract The mechanism of the conversion of vinylazides into 2H-azirines is examined by use of ab initio MO calculations. It is ascertained that vinylnitrenes have very weak bonds between the vinylazides and nitrogen molecule parts. It seems to decompose readily into the two fragments.
Tokio Yamabe +5 more
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Abstract The mechanism of the conversion of vinylazides into 2H-azirines is examined by use of ab initio MO calculations. It is ascertained that vinylnitrenes have very weak bonds between the vinylazides and nitrogen molecule parts. It seems to decompose readily into the two fragments.
Tokio Yamabe +5 more
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A Simple Green Procedure for the Synthesis of 2H‐Azirines.
ChemInform, 2003AbstractFor Abstract see ChemInform Abstract in Full Text.
Pradeep N.D Singh +2 more
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Conical intersections and photoreactions of 2H-azirines
Chemical Physics, 2000Abstract CASSCF calculations were performed on the nπ * - and ππ * -excited states of 2 H -azirine as well as some alkyl-substituted 2 H -azirines. An S 1 /S 0 conical intersection (CI) was located, through which a direct formation of nitrile ylide can occur.
Christian Bornemann, Martin Klessinger
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