Results 41 to 50 of about 85,785,133 (147)

An HF-Nickel-R3Al Catalyst System for Producing High Cis-1,4-Polybutadiene

open access: yes, 1972
A relatively new, high cis-1,4-polybutadiene and a novel trialkylaluminumnickel-HF catalyst system have been described. This polybutadiene is unique in that it possesses high tack and has exceptionally good processing qualities; the carbon black-loaded ...
M. C. Throckmorton, F. S. Farson
core   +1 more source

Conjugated Polymers Engineered for Flexible/Stretchable Electronics

open access: yesJournal of Polymer Science, EarlyView.
This review highlights glass transition temperature (Tg) as the central parameter linking molecular structure to device performance in conjugated polymers. By tuning backbone rigidity, side‐chain architecture, and dynamic bonding, Tg governs the balance between π–π stacking–enabled charge transport and mechanical compliance.
Yunchong Yang   +5 more
wiley   +1 more source

Influence of external nitrogen-containing donors on polymerization behavior of neodymium-based cis-1,4-polybutadiene rubber

open access: yesHecheng xiangjiao gongye
"Neodymium(Nd)-based catalyst in butadiene (Bd) polymerization has drawn interests due to its availability in affording higher cis-1,4-unit selectivity than transition metal (Ti, Co, Ni, etc.)-based catalysts[1-2].
LI Xin1, DONG Jing2, HAN Zhuo-ling1, WANG Feng1, ZHANG Xue-quan1, LIU Heng1*
doaj   +1 more source

The Long Trajectory of Rubber Physics: 3500+ Years and Counting

open access: yesJournal of Polymer Science, EarlyView.
Natural rubber's trajectory is traced from Mesoamerican use of Castilla elastica through vulcanization and the pneumatic tire to macromolecular physics and modern solid‐state refrigeration. Illustrations of C. elastica and an H. brasiliensis plantation frame the historical progression from indigenous material, then industrial crop and on to advanced ...
Gregory B. McKenna
wiley   +1 more source

Controlled synthesis of neodymium-based cis-1,4-polybutadiene rubber bearing polystyrene microblock

open access: yesHecheng xiangjiao gongye
A series of neodymium-based cis-1,4-polybutadiene rubbers bearing polystyrene microblocks were prepared by adding styrene monomer in aging stage of neodymium-based catalyst, the effects of different styrene amount on the polyme-rization behavior and ...
ZHENG Hao, WANG Feng, ZHANG Xue-quan, LIU Heng
doaj   +1 more source

Effect of Hydroxyl‐Terminated Polybutadiene Grade on Rheology and Settling of High‐Solids Mixtures of Mock Propellants

open access: yesPropellants, Explosives, Pyrotechnics, EarlyView.
ABSTRACT The most common binder used in composite rocket propellants is based on the pre‐polymer hydroxyl‐terminated polybutadiene (HTPB). It has been shown to have excellent mechanical properties and a long life once crosslinked, and studies have examined the kinetics of crosslinking and pot life of energetic formulations with HTPB.
Laurel Hilger   +2 more
wiley   +1 more source

Embedded Direct Ink Writing of Thermoset and Elastomeric Polymers via Frontal Polymerization

open access: yesAdvanced Functional Materials, Volume 36, Issue 85, 22 October 2026.
Embedded frontal polymerization direct ink writing (FP‐DIW) combines frontal ring‐opening metathesis polymerization with embedded 3D printing to decouple deposition from curing. A yield‐stress support bath stabilizes low‐viscosity inks, while on‐demand thermal initiation enables controlled front propagation. This approach expands the accessible feature
Mohammad Tanver Hossain   +12 more
wiley   +1 more source

Stress Transfer Within Microphase‐Separated Structures: A Post‐Synthetic Strategy to Impart Mechanoresponsiveness to Block Copolymer Materials

open access: yesAdvanced Materials, Volume 38, Issue 57, 13 October 2026.
A domain‐engineered post‐functionalization strategy is presented to impart mechanochromism to styrene–butadiene–styrene (SBS) block copolymers by simple blending with a tetraarylsuccinonitrile (TASN) mechanophore‐containing polystyrene (PS‐TASN‐PS). The resulting materials exhibit reversible fluorescence under tensile deformation while preserving, or ...
Kuniaki Ishizuki   +3 more
wiley   +1 more source

Architecting nano‐Al/HMX/CuO energetic micro‐units unlocks superior interface and highly efficient combustion

open access: yesInfoMat, Volume 8, Issue 10, October 2026.
Improving the dispersion of nano‐aluminum is of great importance in explosives and propellants. The spherical Al/HMX/CuO energetic micro‐units were prepared using microchannel technology, which significantly improved the uniformity and dispersion of nano‐Al. It also enhanced the mass and heat transfer efficiency between the fuel and oxidizer components,
Gazi Hao   +12 more
wiley   +1 more source

The Possibility of Using Grafted Waste Rubber

open access: yes, 1991
With the addition of 20 phr of BR granulate grafted with ethyl acrylate by the redox or gamma irradiation method to polyacrylic rubber compound, the properties of the rubber worsened, but remained within the range of properties characteristic for these ...
F. Ranogajec   +4 more
core   +1 more source

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