Results 221 to 230 of about 1,948,465 (288)

(Poly)Borylated Species as Modern Reactive Groups toward Unusual Synthetic Applications

open access: yesAngewandte Chemie, EarlyView.
In this review, we spotlight recent breakthroughs in α‐polyboron‐substituted carbon‐centered intermediates (carbanion, carbocation, radical, and carbene) and polyborylated alkenes. By bridging fundamental reactivity with the application potential of these extraordinary species, we hope this review will serve as a roadmap for harnessing these unique ...
Nadim Eghbarieh   +5 more
wiley   +1 more source

Dual Circularly Polarized Luminescence from Chiral Boron‐Embedded Polycyclic Aromatic Hydrocarbons

open access: yesAngewandte Chemie, EarlyView.
Boron‐embedded polycyclic aromatic hydrocarbons featuring an asymmetric boron center coordinated by a proximal P═O group were synthesized. Anthracene‐fused boracyclic derivatives show dual circularly polarized luminescence (CPL) arising from excited‐state P═O⋯B dissociation, which converts point chirality into C−B axial chirality.
Tatsuya Mori   +6 more
wiley   +1 more source

CRISPR-RfxCas13d screening uncovers Bckdk as a post-translational regulator of maternal-to-zygotic transition in teleosts. [PDF]

open access: yesEMBO J
Hernández-Huertas L   +10 more
europepmc   +1 more source

Multidirectional Charge Separation in Self‐Assembled Aggregates of Perylenebisimide‐Porphyrin Bola‐Supra‐Amphiphiles

open access: yesAngewandte Chemie, EarlyView.
Stable aggregates of a new hydrogen‐bond mediated porphyrin‐perylenebisimide (PBI) bola‐type supra‐amphiphile have been synthesized by lyophilization of solutions of both single molecules in THF/water mixtures, followed by redispersion in pure water. Cryogenic transmission electron microscopy verifies the spherical morphology.
Erik J. Schulze   +6 more
wiley   +1 more source

Temperature‐Responsive Near‐Infrared Emission Enabled by Reversible π‐Umpolung with an Alkenyl‐Strapped Diarylboryl Unit

open access: yesAngewandte Chemie, EarlyView.
Coordination of a Lewis base switches an electron‐accepting tricoordinate boron center into an electron‐donating tetracoordinate one. An alkenyl‐strapped diphenylthienylboryl π‐system undergoes phosphine‐induced reversible π‐umpolung, where transformation from an acceptor–acceptor–acceptor framework to a donor–acceptor–donor system gives rise to ...
Satoru Kitamura   +2 more
wiley   +1 more source

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