Results 121 to 130 of about 159,723 (195)

Alkyl Bismuth Cations: Synthesis, Characterization, and Application as Z‐Type Ligands

open access: yesChemistry – A European Journal, EarlyView.
Rare examples of alkyl bismuth cations [BiR2(SbF6)] are presented, including cyclopropyl ligands and a bismacyclic structure. The bismuth‐centered Lewis acids act as Z‐type ligands toward the electron‐rich platinum atom in [Pt(PCy3)2], generating a set of metal‐only Lewis pairs. The structural and spectroscopic properties of these rare types of bismuth
Johannes Schwarzmann   +7 more
wiley   +1 more source

Mimicking The Photosynthetic Special Pair With Aluminum(III) Porphyrin Homodimer – Fullerene (C60) Supramolecular Assemblies Capable of Long‐Lived Charge Separation

open access: yesChemistry – A European Journal, EarlyView.
The axial‐bonding of aluminum(III) porphyrins was used to create two covalently linked special‐pair mimics to probe charge‐transfer between a porphyrin dimer and a C60 unit for artificial photosynthesis. Although excitonic coupling between the porphyrins is weak, incorporation of a second porphyrin markedly increases both the yield and lifetime of the ...
Stefan Charon   +7 more
wiley   +1 more source

Data‐driven simulation of crude distillation using Aspen HYSYS and comparative machine learning models

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Integrated Aspen HYSYS–machine learning framework for predicting product yields and quality variables. Abstract Crude oil refining is a complex process requiring precise modelling to optimize yield, quality, and efficiency. This study integrates Aspen HYSYS® simulations with machine learning techniques to develop predictive models for key refinery ...
Aldimiro Paixão Domingos   +3 more
wiley   +1 more source

Composite membranes comprising of polymeric and molecular amines embedded in poly(vinyl alcohol) matrices to facilitate CO2/H2 separation

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Polymeric and molecular amines embedded in hygroscopic matrices to facilitate CO2 transport for CO2/H2 separation. Abstract This work dealt with composite membranes comprising of polyvinylamine (PVAm) and triethylenetetramine (TETA) embedded in poly(vinyl alcohol) (PVA) for CO2/H2 separation via facilitated transport of CO2, where polymeric and ...
Steve Yijie Hu, Kean Wang, Xianshe Feng
wiley   +1 more source

Economic and environmental implications of the development of UASB reactors in Mexico for sustainable industrial wastewater treatment

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract The objective of this work is to demonstrate that the inclusion of an up‐flow anaerobic sludge bed (UASB reactor) within an industrial wastewater treatment plant reduces the plant's investment and operating costs compared to a system based solely on conventional complete‐mix activated sludge (CMAS), operating under the same design principles ...
Juan Manuel Morgan‐Sagastume   +1 more
wiley   +1 more source

Asymptotic properties of cross‐classified sampling designs

open access: yesCanadian Journal of Statistics, EarlyView.
Abstract We investigate the family of cross‐classified sampling designs across an arbitrary number of dimensions. We introduce a variance decomposition that enables the derivation of general asymptotic properties for these designs and the development of straightforward and asymptotically unbiased variance estimators.
Jean Rubin, Guillaume Chauvet
wiley   +1 more source

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