Results 31 to 40 of about 29,309 (59)

Using Cyclodextrins to Encapsulate Oxygen-Centered and Carbon-Centered Radical Adducts: The Case of DMPO, PBN, and MNP Spin Traps

open access: yes, 2016
We present electron spin resonance (ESR) experiments that describe the interaction of β-cyclodextrin (β-CD) with spin adducts of three spin traps: 5,5-dimethyl-1-pyrroline N-oxide (DMPO), N-tert-butyl-α-phenylnitrone (PBN), and 2-methyl-2-nitrosopropane (
Shulamith Schlick (1659718)   +1 more
core   +1 more source

一种制备2,6-二叔丁基萘的方法

open access: yes, 2009
一种制备2,6-二叔丁基萘(DTBN)的方法。本发明中采用叔丁基为取代基团进行萘择形烷基化反应,得到2,6-DTBN组分含量较高的混合液,该混合液可以通过低级醇重结晶方法进行分离提纯,获得高纯度的 2,6-DTBN结晶。该方法克服了采用小体积取代基团如甲基、乙基、异丙基等进行萘择形烷基化反应时,二烷基萘(DAN)选择性差,2,6-/2,7-DAN 低,而且目的产物2,6-DAN分离困难的问题。在草酸络合脱铝改性的Y 型沸石分子筛催化剂上,萘转化率可达到70摩尔%,2,6-/2,7-DTBN比接近9.0 ...
刘中民, 张新志, 王莹利, 许 磊
core  

HY Zeolite Modified by Liquid Silane Deposition and Its Catalytic Activity in Selective tert-Butylation of Naphthalene

open access: yes, 2008
HY zeolite was modified by chemical liquid deposition with i-C(4)H(9)Si(OC(2)H(5))(3) and a hydrothermal treatment. The samples were characterized by X-ray diffraction. N(2) adsorption, and pulse mass analysis to investigate the influence of modification
Liu Zhongmin   +4 more
core  

Shape-Selective Catalysis in the Alkylation of Naphthalene: Steric Interaction with the Nanospace of Zeolites

open access: yes, 2015
Steric interaction of reagents with nanospace of zeolites was studied in alkylation: isopropylation, sec-butylation, and tert-butylation of naphthalene (NP) over several large-pore zeolites to elucidate the mechanism of shape-selective catalysis ...
Vinu, Ajayan, Sugi, Yoshihiro
core   +1 more source

Manufacturing facility for nylon-6,6 [PDF]

open access: yes, 2017
The purpose of this project is to evaluate the feasibility of constructing a nylon-6,6 plant from grassroots in Calvert City, Kentucky. While designing, evaluating, and optimizing the production process of nylon-6,6, there were several conclusions that ...
Gade, Noah   +3 more
core  

Synthesis of 6,6'-methylenebisquinazolinones and 7,7′-methylenebis-1,4-benzodiazepine- 2,5-diones

open access: yes, 2002
2405-2409New C-C linked bisquinazolinones, 6,6'-methylenebis-2-aryl-3-methyl-1,2,3,4-tetrahydroquinazolin-4(3H)-one 4, 6,6'-methylenebis-2-alkyl-3-methyl-3,4-dihydroquinazoli n-4(3H)-one 6, 6,6'-methylenebis-4-oxo-2-thio-3-aryl-1 ,2,3,4-tetrahydro ...
Reddy, P Pratap   +5 more
core   +1 more source

Crystal structures of bis- and hexakis[(6,6′-dihydroxybipyridine)copper(II)] nitrate coordination complexes

open access: yes, 2015
Two multinuclear complexes synthesized from Cu(NO3)2 and 6,6′-dihydroxybipyridine (dhbp) exhibit bridging nitrate and hydroxide ligands. The dinuclear complex (6,6′-dihydroxybipyridine-2κ2N,N′)[μ-6-(6-hydroxypyridin-2-yl)pyridin-2-olato-1:2κ3N,N′:O2](μ ...
Matthias Zeller   +5 more
core   +1 more source

A cis-dioxoruthenium(VI) complex as active oxidant of chloride and organic substrates; preparation, characterization, and reactivity of cis-[Ru VI(6,6′-Cl2bpy)2O2] 2+ (6,6′-Cl2bpy = 6,6′-dichloro-2,2′- bipyridine)

open access: yes, 1987
Oxidation of cis-[RuII(6,6′-Cl2bpy) 2(OH2)2]2+ with CeIV gave cis-[RuVI(6,6′-Cl2bpy)2O 2]2+, isolated as the diamagnetic ClO4 - salt, which rapidly oxidizes Cl- (to Cl2) and a wide variety of organic substrates (tetrahydrofuran to butyrolactone and ...
Che, CM, Leung, WH
core   +1 more source

Morphology Analysis and Mechanical Properties of MWCNT Reinforced Nylon-6,6 Nanofiber Mats by Electrospun Method

open access: yes, 2017
In this study, the production of weight ratios of 1, 3 and 5 % multi-walled carbon nanotubes (MWCNT) reinforced / unreinforced Nylon 6,6 (N-6,6) nanofiber mats was carried out by electro spun method.
Fırat Durmuş   +3 more
core   +1 more source

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