Results 91 to 100 of about 3,133 (222)

Synthesis and Characterization of Transition Metal Complexes Supported by Phosphorus Ligands Obtained Using Hydrophosphination of Cyclic Internal Alkenes

open access: yesMolecules
The design and study of rich, bulky phosphorus ligands is a key area of research for homogeneous catalysis. Here, we describe an original strategy using a hydrophosphination reaction to produce phosphines of interest for coordination chemistry and ...
Victoria Mechrouk   +4 more
doaj   +1 more source

Comparison of PCBs and PAHs levels in European coastal waters using mussels from the Mytilus edulis complex as biomonitors

open access: yesOceanologia, 2015
Mussels from the Mytilus edulis complex were used as biomonitors for two groups of organic pollutants: polychlorinated biphenyls (PCBs, congeners: 28, 52, 101, 118, 138, 153 and 180) and polycyclic aromatic hydrocarbons (PAHs, naphthalene, acenaphthylene,
Michał Olenycz   +6 more
doaj   +1 more source

Crystal structure of 8-[7,8-bis(4-chlorobenzoyl)-7H-cyclopenta[a]acenaphthylen-9-yl]naphthalene-1-carboxylic acid

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2015
The title compound, C40H22Cl2O4, was formed by a Michael–Aldol domino reaction sequence, which coupled acenaphthenequinone with 4-chloroacetophenone in the presence of KOH in methanol.
Jomon P. Jacob   +3 more
doaj   +1 more source

Concentration dependence of the steric course of bromine addition to acenaphthylene. A product and kinetic study

open access: yes, 1997
The ratios of Z- to E-1,2-dibromo-1,2-dihydroacenaphthylene obtained in the bromination of acenaphthylene in chlorinated solvents have been determined by NMR as a function of the reagents concentrations.
Bellucci G   +4 more
core   +1 more source

Mechanism of Photodimerization of Acenaphthylene

open access: yes, 2016
The mechanism of photodimerization of acenaphthylene (ACN) has been investigated in order to elucidate the roles of the singlet and the triplet excited states of ACN in the formation of the Z- and E-dimers in several solvents.
Naoki Haga (3040248)   +2 more
core   +1 more source

Dye-sensitized solar cells with 13% efficiency achieved through the molecular engineering of porphyrin sensitizers [PDF]

open access: yes, 2014
Dye-sensitized solar cells have gained widespread attention in recent years because of their low production costs, ease of fabrication and tunable optical properties, such as colour and transparency. Here, we report a molecularly engineered porphyrin dye,
Peng Gao   +24 more
core   +1 more source

A Regioselective Multicomponent Approach for the Synthesis of Novel 2-Acetyl-4-phenylquinoline Designed Monospiro-Pyrrolidine and Thiapyrrolizidine Hybrids

open access: yesHeteroatom Chemistry
A convenient approach for the synthesis of 2-acetyl-4-phenylquinoline designed monospiro-pyrrolidine/thiapyrrolizidine hybrids has been achieved via a 1,3-dipolar cycloaddition reaction of various azomethine ylides derived from isatin/acenaphthylene-1,2 ...
Satheeshkumar Rajendran   +2 more
doaj   +1 more source

Construction of acenaphthylenes via C−H activation-based tandem penta- and hexaannulation reactions

open access: yesNature Communications
Acenaphthylene-containing polycyclic aromatic hydrocarbons (AN-PAHs) are noteworthy structural motifs for organic functional materials due to their non-alternant electronic structure, which increases electron affinity.
Jian Li   +6 more
doaj   +1 more source

The Mechanism of Formation of Acenaphthylene on Pyrolysis of 8-Methylcyclobuta[a]naphthalene-1,2-dione

open access: yes, 1989
Flash vacuum pyrolysis of the l-13C labelled title dione (13) gives acenaphthylene labelled predominantly at C4 (65.9%) and C1 (27.6%). This is in accord with the intermediacy of the (labelled) acyloxycarbene (5), the lactone (6) and the carbene ...
RFC Brown, FW Eastwood, BE Kissler
core   +1 more source

A Convenient Synthesis of Fused Tetrahydroazocines from Acenaphthylene-1,2-dione, Proline, and Acetylenic Esters

open access: yes, 2017
A synthesis of dialkyl (12E,14E)-7-oxo-10,11-dihydro-7H,9H-azocino[2,1-a]benzo[de]isoquinoline-13,14-dicarboxylates through a 1,3-dipolar cycloaddition reaction of azomethine ylides, generated in situ from proline and acenaphthylene-1,2-dione, with ...
Mohammad Halvagar   +2 more
core   +1 more source

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