Results 161 to 170 of about 3,133 (222)
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Cationic polymerization of acenaphthylene and methyl acenaphthylenes
Polymer, 1973Abstract Cationic polymerization of acenaphthylene was studied both by experimental methods and theoretical calculations. Very pure acenaphthylene was obtained by double sublimation and its polymerization kinetics were studied with SnCl 4 as initiator.
S. Cohen, P. Belliard, E. Marechal
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Ozonolysis of acenaphthylene and 1-substituted acenaphthylenes
The Journal of Organic Chemistry, 1990The ozonolysis of title compound in carbon tetrachloride, acetonitrile, acetic acid, and trifluoroethanol revealed that the ozonide yield was much higher in reactions in protic solvents than in aprotic solvents. Such an assistance of the protic solvents on the ozonide formation was not observed in the case of the more bulky 1 ...
Toshiya Sugimoto +2 more
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Tridecacyclene: A Cyclic Tetramer of Acenaphthylene
Chemistry – A European Journal, 2016AbstractIn this manuscript, we describe the single‐step preparation of a cyclic tetramer of acenaphthylene through a Lewis acid‐catalyzed aldol cyclization of 1‐acenaphthenone. The previously unexplored cyclic tetramer material differs from the better‐known cyclic trimer, decacyclene, due to the presence of a central eight‐membered ring.
Daniel P. Sumy +4 more
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Inner cavity of Pd-nanocage has been used as a reaction vessel for performing triplet sensitized [2+2] photodimerization of acenaphthylene using water soluble xanthene dyes (Eosin Y and Rose Bengal) as sensitizers, and [4+4] photodimerization of 9 ...
V Ramamurthy
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ChemInform Abstract: Ozonolysis of Acenaphthylene and 1‐Substituted Acenaphthylenes.
ChemInform, 1990AbstractThe ozonolysis of the acenaphthylenes (I) in protic solvents, e.g. methanol (II), yields a mixtures of the ozonide (III) and the peroxide (IV).
T. SUGIMOTO, M. NOJIMA, S. KUSABAYASHI
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Photodimerisation of acenaphthylene in a clay microenvironment
Photochemical & Photobiological Sciences, 2003The photochemical dimerisation of acenaphthylene in the presence of various cation-exchanged bentonite clays has been studied. While the cis-dimer is the predominant product when smaller cations are present in the clay interlayer, the presence of heavier atoms in the clay favors the trans-dimer. Synthetic anionic hydrotalcite clays are also found to be
Durairajan, Madhavan, Kasi, Pitchumani
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Decomposition of Acenaphthylene by Ultrasonic Irradiation
Analytical Chemistry, 1998Polycyclic aromatic hydrocarbons were extracted from a soil sample using ultrasound and dichloromethane-, cyclohexane-, and toluene-water mixtures. It was found that when dichloromethane is used as an extractant, acenaphthylene reacts with the solvent. Several chlorinated and oxygenated derivatives were identified.
Leonhardt, E., Stahl, R.
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Polymerization of acenaphthylene by BF3-Et2O
European Polymer Journal, 1971Abstract The polymerization of acenaphthylene initiated by BF3-Et2O has been studied in ethylene dichloride and in methylene dichloride. The influence of monomer and catalyst concentrations, as well as that of the temperature, on the polymerization rate and on the polymer molecular weight has been investigated.
P. GIUSTI +3 more
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THE PHOTOCYCLOADDITION OF ACENAPHTHYLENE WITH TETRACYANOETHYLENE
Chemistry Letters, 1972Abstract Irradiation of a solution of acenaphthylene and tetracyanoethylene yielded the cycloadduct. The excited singlet acenaphthylene is suggested to be the reactive species.
Yasuhiko Shirota +2 more
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The activation and transformations of acenaphthylene by osmium carbonyl cluster complexes
The reaction of Os 3(CO) 10(NCMe) 2 ( 1) with an excess of acenaphthylene at room temperature provided the complex Os 3(CO) 10(μ-H)(μ–η 2-C 12H 7) ( 2). Compound 2 contains a σ–π coordinated acenaphthyl ligand bridging an edge of the cluster.
Richard D Adams +2 more
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