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Silicon-Mediated Coupling of Carbon Monoxide, Ammonia and Primary Amines to Form Acetamides.
Angewandte Chemie, 2019For the first time, a direct transformation of CO, NH3 and primary amines into acetamides, mediated by a main-group element (silicon), is reported. Starting point is the selective deoxygenative reductive homocoupling of two CO molecules by the Fc-bis ...
Marcel-Philip Luecke +4 more
semanticscholar +1 more source
Synthesis of acetamides using CO2, methanol, H2 and amines
Green Chemistry, 2019Acetamides can be synthesized from CO2, methanol, H2 and corresponding amines, which is a new route for their production.
Jingjing Zhang +6 more
semanticscholar +1 more source
Activity of acetamide in acetamide-calcium nitrate melt solutions
Journal of Solution Chemistry, 1994Activity coefficients of acetamide in acetamide-calcium nitrate melt solutions were determined from cryoscopic data in the concentration range O to 0.151 mole fraction of calcium nitrate. Enthalpies of melting and melting point depressions were obtained from DSC measurements.
Ružica Nikolić, Gordana Ristić
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O-Glycosylation Enabled by N-(Glycosyloxy)acetamides.
Journal of Organic Chemistry, 2018A novel glycosylation protocol has been established by using N-(glycosyloxy)acetamides as glycosyl donors. The N-oxyacetamide leaving group in donors could be rapidly activated in the presence of Cu(OTf)2 or SnCl4 under microwave irradiation.
Miao Liu, Bohan Li, Decai Xiong, X. Ye
semanticscholar +1 more source
Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry, 2019
An efficient and metal-free coupling reaction has been developed that affords acetamides from the corresponding aryl amines and acetonitrile. This method tolerates a wide range of functional groups and is selective toward aryl amines.
Yao‐Fu Zeng +7 more
semanticscholar +1 more source
An efficient and metal-free coupling reaction has been developed that affords acetamides from the corresponding aryl amines and acetonitrile. This method tolerates a wide range of functional groups and is selective toward aryl amines.
Yao‐Fu Zeng +7 more
semanticscholar +1 more source
, 2017
Radical cascade difluoroacetamidation of N-(arylsulfonyl)acrylamides with α,α-difluoro-α-(TMS)-acetamides has been achieved for the first time. This CuBr-mediated transformation is easy to perform, generates high yields and shows a good substrate scope ...
Kai Liu +4 more
semanticscholar +1 more source
Radical cascade difluoroacetamidation of N-(arylsulfonyl)acrylamides with α,α-difluoro-α-(TMS)-acetamides has been achieved for the first time. This CuBr-mediated transformation is easy to perform, generates high yields and shows a good substrate scope ...
Kai Liu +4 more
semanticscholar +1 more source
Journal of Thermal Analysis, 1990
Molten mixtures of acetamide and ammonium sulfamate (indicated here AS) are reacted at mole ...
F. Castellani, G. Berchiesi, V. Bartocci
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Molten mixtures of acetamide and ammonium sulfamate (indicated here AS) are reacted at mole ...
F. Castellani, G. Berchiesi, V. Bartocci
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Adamantylation of N-aryl and N-arylalkyl acetamides in trifluoroacetic acid
Russian chemical bulletin, 2020I. Novakov +9 more
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