Asian Journal of Organic Chemistry, EarlyView.Ir‐catalyzed sulfur‐directed C─H alkenylation of alkynoates proceeded by using aryl methallyl sulfides. When DMAD was employed, 1,3‐dienes were initially formed and subsequently underwent thermal 1,5‐sigmatropic rearrangement to yield secondary products with high stereoselectivitiy.
Takanori Shibata, Haru Marumo
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Exclusive roaming mechanism for the Cl + C<sub>2</sub>H<sub>2</sub>→C<sub>2</sub>H + HCl bimolecular reaction. [PDF]
Nat CommunBai Y +7 more
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New Infra-Red Bands Photographed in the Absorption Spectrum of Acetylene [PDF]
, 1932 W. Lochte‐Holtgreven, Eric Eastwood
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A Triptycene‐Based Cage Host for Aromatic Hydrocarbon Guests
Asian Journal of Organic Chemistry, EarlyView.A molecular cage consisting of two tripodal triptycene units and three diphenylacetylene linkers includes aromatic guests such as anthracene, acenaphthylene, and pyrene into the cavity. The association constants of the host–guest complexation were determined by the 1H NMR titration.
Takuji Mitani +4 more
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Synthesis and characterization of novel nanomaterial Zn-MOF-NH<sub>2</sub>-ZIF-8@Cu based on MOF-on-MOF architecture and Cu nanoparticle as a stable nanocatalyst in solvent-free A<sup>3</sup> coupling reaction. [PDF]
Sci RepKiani A, Alinezhad H.
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On the Hydrogenation and Polymerisation Reaction of Acetylene. IV. Kinetics of Polymerisation by Use of Thermal Separation Column. II [PDF]
, 1943 Osamu Kimura, Kôzô Hirota
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Asian Journal of Organic Chemistry, EarlyView.A single‐crystalline layered framework composed of a low‐density hydrogen‐bonded hexagonal network (HexNet) sheet was constructed using a C3‐symmetric π‐conjugated building block molecule possessing a macrocyclic core expanded by diethynylterphenyl linkers and peripheral six carboxy phenyl groups.
Yuzuru Kanetada +4 more
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Enhancing the Cumulene Character of One-Dimensional Acetylene-Based Systems by Stimuli-Induced Planarization of Their Two Pro-diradicaloid Cyclopenta[h,i]aceanthrylene Units. [PDF]
Angew Chem Int Ed EnglFernández ÁC +5 more
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ACETYLENE, the NEW ILLUMINANT, and he DANGERS ARISING from its INHALATION [PDF]
, 1898 Thomas Oliver
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Angewandte Chemie, EarlyView.Tetra‐ortho‐Azobenzenes (TOABs) in broad daylight: in recent years, TOAB photoswitches became indispensable tools for all‐visible‐light manipulation of chemistry, biology and materials. This review explores their unique photochemical properties, design and synthetic approaches, offering support in choosing a TOAB for a given application.
Francesca Cardano +2 more
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