Results 41 to 50 of about 4,964,055 (321)

State-to-state endothermic and nearly thermoneutral reactions in an ultracold atom-dimer mixture [PDF]

open access: yesPhys. Rev. A 100, 032706 (2019), 2017
Chemical reactions at ultracold temperature provide an ideal platform to study chemical reactivity at the fundamental level, and to understand how chemical reactions are governed by quantum mechanics. Recent years have witnessed the remarkable progress in studying ultracold chemistry with ultracold molecules.
arxiv   +1 more source

The dual nature of TDC – bridging dendritic and T cells in immunity

open access: yesFEBS Letters, EarlyView.
TDC are hematopoietic cells combining dendritic and T cell features. They reach secondary lymphoid organs (SLOs) and peripheral organs (liver and lungs) after FLT3‐dependent development in the bone marrow and maturation in the thymus. TDC are activated and enriched in SLOs upon viral infection, suggesting that they might play unique immune roles, since
Maria Nelli, Mirela Kuka
wiley   +1 more source

Mapping the Space of Chemical Reactions Using Attention-Based Neural Networks [PDF]

open access: yesarXiv, 2020
Organic reactions are usually assigned to classes containing reactions with similar reagents and mechanisms. Reaction classes facilitate the communication of complex concepts and efficient navigation through chemical reaction space. However, the classification process is a tedious task. It requires the identification of the corresponding reaction class
arxiv  

Leveraging current insights on IL‐10‐producing dendritic cells for developing effective immunotherapeutic approaches

open access: yesFEBS Letters, EarlyView.
In vivo IL‐10 produced by tissue‐resident tolDC is involved in maintaining/inducing tolerance. Depending on the agent used for ex vivo tolDC generation, cells acquire common features but prime T cells towards anergy, FOXP3+ Tregs, or Tr1 cells according to the levels of IL‐10 produced. Ex vivo‐induced tolDC were administered to patients to re‐establish/
Konstantina Morali   +3 more
wiley   +1 more source

Conversion of Cellobiose to Formic Acid as a Biomass‐Derived Renewable Hydrogen Source Using Solid Base Catalysts

open access: yesChemistryOpen
Formic acid is considered a promising hydrogen carrier. Biomass‐derived formic acid can be obtained by oxidative decomposition of sugars. This study explored the production of formic acid from cellobiose, a disaccharide consisting of d‐glucose linked by ...
Ikuto Yoshiki   +4 more
doaj   +1 more source

Experimental and Theoretical Studies on the Functionalization Reactions of 4-Benzoyl-1,5-Diphenyl-1H-Pyrazole-3-Carboxylic Acid and Acid Chloride with 2,3-Diaminopyridine

open access: yesMolecules, 2005
The 1H-pyrazole-3-carboxylic acid 2 was converted in good yield (69%) into the corresponding 1H-pyrazole-3-carboxamide 5 via reaction of the acid chloride 3 with 2,3- diaminopyridine (4).
Elif Demir   +2 more
doaj   +1 more source

FoxO1 signaling in B cell malignancies and its therapeutic targeting

open access: yesFEBS Letters, EarlyView.
FoxO1 has context‐specific tumor suppressor or oncogenic character in myeloid and B cell malignancies. This includes tumor‐promoting properties such as stemness maintenance and DNA damage tolerance in acute leukemias, or regulation of cell proliferation and survival, or migration in mature B cell malignancies.
Krystof Hlavac   +3 more
wiley   +1 more source

A Lewis Acid-Promoted Michael Addition and Ring-Expansion Cascade for the Construction of Nitrogen-Containing Medium-Sized Rings

open access: yesMolecules, 2023
A Lewis acid-promoted annulation of azadienes and cyclobutamines was developed. This reaction proceeded through Michael addition and ring-expansion cascade, affording the corresponding nitrogen-containing medium-sized rings with a broad scope in moderate
Jiaming Wang, Jia Li, Changgui Zhao
doaj   +1 more source

DIRECT EVIDENCE FOR AMMONIUM ION FORMATION IN ICE THROUGH ULTRAVIOLET-INDUCED ACID–BASE REACTION OF NH3 WITH H3O+

open access: yes, 2010
We present direct evidence for ammonium ion (NH4+) formation through ultraviolet (UV) photolysis of NH3–H2O mixture ice that does not contain acids. NH4+ forms by the reaction of NH3 with protonic defects (H3O+) in the UV-photolyzed ice. Our observations
Eui-seong Moon   +4 more
semanticscholar   +1 more source

Universal kinetics of imperfect reactions in confinement [PDF]

open access: yesarXiv, 2021
Chemical reactions generically require that particles come into contact. In practice, reaction is often imperfect and can necessitate multiple random encounters between reactants. In confined geometries, despite notable recent advances, there is to date no general analytical treatment of such imperfect transport-limited reaction kinetics.
arxiv  

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