Electrochemically cooperative halogen-cation delivery enables modular electrophilic haloesterification of both activated and unactivated alkenes. [PDF]
Xu HH +5 more
europepmc +1 more source
The structural design strategy employing the Y6‐BO interfacial lamination suppresses dark current by limiting solvent‐induced interfacial damage through the formation of uniformly arranged interfaces while optimizing charge transport to achieve superior detectivity.
Jihyun Lim +4 more
wiley +1 more source
Structure-reactivity based control of radical-mediated degradation in thiol-Michael hydrogels.
Kirkpatrick BE +7 more
europepmc +1 more source
The Italian Trend of Contact Allergy to 2-Hydroxyethyl Methacrylate: Is the Current European Legislation Working? [PDF]
Caroppo ES +14 more
europepmc +1 more source
Photolytic Hydrophosphination: Insights Into Catalyzed and Uncatalyzed Processes
Catalyst‐free photolytic hydrophosphination is demonstrated for vinyl arenes and activated alkenes in polar protic (alcohol) solvents. These reactions appear to be closed‐shell, affirming that even ambient light can impact a reaction—a potentially broad influence on even mundane reactions.
Emma J. Finfer +2 more
wiley +1 more source
Regio- and Enantioconvergent Hydroallylation of Acrylates Enabled by γ-Silyl-Substituted Allyl Acetates. [PDF]
Suzuki H +4 more
europepmc +1 more source
Breaking the Mold: Electrophilic Hydrophosphanation Emerges
Electrophilic hydride attack on the olefin, instead of the classical nucleophilic addition by a phosphanido ligand, is unveiled in rhodium‐catalyzed olefin hydrophosphanation. This hydride‐driven pathway operates for both activated and inactivated olefins, with transition states characterized by elongated Rh─H bonds and nascent C─H bond formation ...
Víctor Varela‐Izquierdo +4 more
wiley +1 more source
Exploring Acrylic Acid as an Oxirane Nucleophile: Direct Access to Poly(β-Hydroxy Acrylates). [PDF]
Montanari C +3 more
europepmc +1 more source
N‐Aryl Acridone Derivatives as Effective Catalysts for Energy Transfer Reactions
Acridones derivatives have high triplet energy, are simple accessible, and could be used in challenging [2+2] ENT reactions. ABSTRACT Organic photocatalysts capable of promoting high‐energy triplet energy transfer (EnT) remain limited, particularly for demanding [2+2] photocycloaddition reactions.
Francesco Calogero +8 more
wiley +1 more source
Refining the Amino Reactivity-Based Identification of Respiratory Sensitizers. [PDF]
Simoneit M +3 more
europepmc +1 more source

