Sequential curing of thiol-acetoacetate-acrylate thermosets by latent Michael addition reactions [PDF]
Thiol-acetoacetate-acrylate ternary dual-curing thermosets were prepared by a sequential process consisting of thiol-Michael addition to acrylates at room temperature followed by Michael addition of acetoacetates to acrylates at moderately elevated ...
Fernández Francos, Xavier +5 more
core +2 more sources
Hyperbranched urethane-acrylates [PDF]
The synthesis, characterization and UV-curing of hyperbranched urethaneacrylates (HB-UA) were investigated in this study. They were evaluated as oli-gomers in model UV curable coatings.
Tasić Srba +2 more
doaj +1 more source
Glycerol as a cheap, safe and sustainable solvent for the catalytic and regioselective β,β-diarylation of acrylates over palladium nanoparticles [PDF]
Herein we show that glycerol can be considered as a promising cheap and green solvent for the regioselective β,β-diarylation of alkenes. Whereas this reaction is generally catalyzed under an inert atmosphere by expensive phosphine or carbene-palladium ...
Barrault, Joel +7 more
core +2 more sources
Synthesis of novel room temperature chiral ionic liquids. application as reaction media for the heck arylation of aza-endocyclic acrylates. [PDF]
New achiral and chiral RTILs were prepared using novel and/or optimized synthetic routes. These new series of imidazolinium, imidazolium, pyridinium and nicotine-derived ionic liquids were fully characterized including differential scanning calorimetry ...
Correia, Carlos R. D. +4 more
core +4 more sources
Automated synthesis of monodisperse oligomers, featuring sequence control and tailored functionalization [PDF]
Long, multifunctional sequence-defined oligomers were obtairred on solid support from a protecting-group-free two-step iterative protocol, based on the inherent reactivity of a readily available molecule containing an isocyanate and a thiolactone ...
Du Prez, Filip +4 more
core +4 more sources
METHACRYLATE AND ACRYLATE ALLERGY IN DENTAL STUDENTS. [PDF]
A multitude of acrylic monomers is used in dentistry, and when dental personnel, patients or students of dental medicine become sensitized, it is of great importance to identify the dental ;acrylic preparations to which the sensitized individual can be ...
Maya Lyapina +4 more
doaj +1 more source
Unwanted Skin Reactions to Acrylates: An Update
Acrylates and methacrylates, though common in a wide variety of products, especially in the dental industry, can cause adverse skin reactions. These compounds, including 2-hydroxyethyl methacrylate, triethylene glycol dimethacrylate, and bisphenol A ...
Liborija Lugović-Mihić +7 more
doaj +1 more source
Airborne contact dermatitis and asthma in a nail art operator
Nail art (creation and decoration of artificial nails) is a growing fashion trend. Proportionally to its popularity, the number of allergic reactions to the materials used has recently increased.
Mario Vaccaro +3 more
doaj +1 more source
Effect of organoclay on the physical properties of UV-curable coatings [PDF]
The combination of UV-curing and nanocomposite technology has been studied to produce cost-effective coatings with superior physical and mechanical properties.
Dalgicdir, Cahit +5 more
core +1 more source
Enantioenriched α-aryl propionic acids are an important class of nonsteroidal anti-inflammatory medications. Here the authors use a visible-light-promoted photoredox/nickel catalyzed method to form such compunds via a three-component alkyl arylation of ...
Pengcheng Qian +7 more
doaj +1 more source

