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Porphyrinoid actinide complexes
Chemical Society Reviews, 2022The diverse coordination modes and electronic features of actinide complexes of porphyrins and related oligopyrrolic systems (referred to as “porpyrinoids”) have been the subject of interest since the 1960s.
Gabriela I. Vargas-Zúñiga +4 more
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Preparation of actinides and actinide compounds
Journal of Magnetism and Magnetic Materials, 1982Abstract Starting materials for actinide research are commercially available oxides. The metals are synthesized by the metallothermic reduction of oxides, halides or carbides. The metals are further refined by vacuum-melting, distillation, van Arkel process or electrorefining to 99.9% purity.
J.C. Spirlet, O. Vogt
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Actinide Organometallic Chemistry
Science, 1976The stoichiometric and catalytic chemistry of metal-organic compounds having actinide-to-carbon bonds is in a stage of rapid growth. Chemical, structural, and bonding characteristics have been identified which differ in interesting and informative ways from those of d -block transition element compounds.
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Uncovering Heavy Actinide Covalency: Implications for Minor Actinide Partitioning
Inorganic Chemistry, 2019Across the actinide period, the stability of the trivalent oxidation state predominates in the heavy actinides, making their chemical nature close to that of rare earth elements. The resemblance in their chemistry poses difficulties in separating heavy actinides from lanthanides, which is a vital separation in the minor actinide partitioning process ...
Aditi Chandrasekar, Tapan K. Ghanty
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Thermodynamic Properties of Actinides and Actinide Compounds
2007The necessity of obtaining accurate thermodynamic quantities for the actinide elements and their compounds was recognized at the outset of the Manhattan Project, when a dedicated team of scientists and engineers initiated the program to exploit nuclear energy for military purposes.
Rudy J. M. Konings +2 more
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