Results 11 to 20 of about 2,642 (182)
Molecules, 2022 A series of exohedral actinide borospherenes, An&Bm, and endohedral borospherenes, An@Bn (An=U, Np, Pu; m = 28, 32, 34, 36, 38, 40; n = 36, 38, 40), have been characterized by density functional theory calculations.
Peng Li +9 more
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Chemistry Teacher International, 2023 Relativistic effects are important to understand the chemistry of heavier elements across the periodic table (PT). Three important relativistic effects are: contraction of s- and p-orbitals (direct relativistic effect), expansion of d- and f-orbitals ...
Das Ankita +3 more
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Journal of Synchrotron Radiation, 2022 N-donor ligands such as n-Pr-BTP [2,6-bis(5,6-dipropyl-1,2,4-triazin-3-yl)pyridine] preferentially bind trivalent actinides (An3+) over trivalent lanthanides (Ln3+) in liquid–liquid separation. However, the chemical and physical processes responsible for
Tim Pruessmann +7 more
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Nature Chemistry, 2017 Suzanne Bart from Purdue University talks to Nature Chemistry about her investigations into the chemistry of actinides, and why she finds them both challenging and rewarding.
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Spectroscopic evaluation of UVI–cement mineral interactions: ettringite and hydrotalcite
Journal of Synchrotron Radiation, 2022 Portland cement based grouts used for radioactive waste immobilization contain high replacement levels of supplementary cementitious materials, including blast-furnace slag and fly ash.
Antonia S. Yorkshire +8 more
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Molecules, 2022 The structure and bonding properties of 16 complexes formed by trivalent f elements (M=U, Np, Pu and lanthanides except for Pm and Pr) with cyclopentadienyl (Cp) and cyclohexylisonitrile (C≡NCy) ligands, (Cp)3M(C≡NCy), were studied by a joint ...
Attila Kovács +2 more
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Sensitivity analysis of minor actinides transmutation to physical and technological parameters
EPJ Nuclear Sciences & Technologies, 2015 Minor actinides transmutation is one of the three main axis defined by the 2006 French law for management of nuclear waste, along with long-term storage and use of a deep geological repository. Transmutation options for critical systems can be divided in
Kooyman Timothée, Buiron Laurent
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He huaxue yu fangshe huaxue, 2022 As a class of typical metal-organic framework materials(MOFs), actinide-based MOFs feature their unique actinide-ligand bonds. However, how these coordination interactions participate in and affect the lattice assembly process of organic ligands remains ...
WANG Shuai +5 more
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Alpha-cluster preformation probability in even-even actinide nuclei
Results in Physics, 2019 The preformation probability of alpha cluster in the even-even actinide nuclei was determined using the cluster-formation model. The actinides chosen were with high and low intensity of alpha-decay mode. The results showed well production of preformation
Norah A.M. Alsaif, Saad M. Saleh Ahmed
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Известия Томского политехнического университета: Инжиниринг георесурсов, 2021 The relevance of the research is determined by the need to developing the method for obtaining mineral-like matrix materials intended for immobilization of the most hazardous radioactive waste of the nuclear industry. The use of the self-propagating high-
Oleg Yu. Dolmatov +2 more
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