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Adiabatic Rate Processes

1980
As we remember (Chapter 2.1), the non-radiative transitions occurring at the same electronic state are called adiabatic transitions. It means that in terms of the Born-Oppenheimer approximation (see Chapter 1.4) the transitions are going on at the same electronic energy hypersurface between two potential energy minima corresponding to two (quasi ...
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Statistical mechanics of adiabatic processes

Physica, 1964
Abstract The thermodynamic equivalence of an Ehrenfest adiabatic process and an isentropic process is investigated by examining the difference between the susceptibilities calculated under isentropic and Ehrenfest adiabatic conditions. It is found that except under quite restrictive conditions this difference does not vanish.
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The travelling salesman problem and adiabatic quantum computation: an algorithm

Quantum Information Processing, 2018
An explicit algorithm for the travelling salesman problem is constructed in the framework of adiabatic quantum computation, AQC. The initial Hamiltonian for the AQC process admits canonical coherent states as the ground state, and the target Hamiltonian ...
T. Kieu
semanticscholar   +1 more source

Adiabatic processes and the equation of state

Physica, 1964
Abstract It is shown that if a system satisfies the conditions for exact equality of its isolated and isentropic susceptibilities, then the system has an equation of state of the Gruneisen form. The much weaker consequences of the generally valid asymptotic equality of the susceptibilities are also discussed.
R.D. Mountain, Martin J. Klein
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Adiabatic Approximation for Scattering Processes

Physical Review, 1956
The adiabatic approximation, frequently utilized in treating bound states of quantum-mechanical systems, is shown to be applicable also to scattering processes in cases for which the number of excited states of the target contributing significantly to the wave function is limited, and for which the time of traversal of the scattered particle through ...
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Adiabatic processes in monatomic gases

The Journal of Chemical Physics, 1988
A kinetic model is used to predict the temperature evolution of a monatomic ideal gas undergoing an adiabatic expansion or compression at a constant finite rate, and it is then generalized to treat real gases. The effects of interatomic forces are considered, using as examples the gas with the square-well potential and the van der Waals gas.
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Electronically Non-adiabatic Processes

2003
So far we have almost entirely dealt with surface structures and processes that correspond to the electronic ground state. This means that we have assumed that the Born-Oppenheimer approximation is justified. Although there are many important processes at surfaces that involve electronic transitions [225,383,384], the status of the theoretical ...
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Adiabatic calorimetry for safety studies in nitration processes

Thermochimica Acta, 1992
Abstract The thermal and chemical evolution of the benzonitrile nitration process under adiabatic conditions were investigated for the reacting mixture: 5.1% benzonitrile 30.9% HNO 3 55.4% H 2 SO 4 and 8.6% H 2 O at a starting temperature of 300 K.
ANDREOZZI, ROBERTO   +3 more
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Adiabatic Processes. Laplace’s Theorem

1977
A process is adiabatic if Q(t) = 0 at all times t at which Q(t) is defined. Any curve in 풟 whose tangent vector in some parametric representation is always orthogonal to the vector field (Λ V , K V ) is called an adiabat.
Subramanyam Bharatha   +1 more
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Adiabatic Processes in Magnetic Materials

2000
The paper discusses the heat generation and absorption in magnetic materials during adiabatic processes (magneto- and elastocaloric effects). The general thermodynamic relations for the elastocaloric effect are derived, and numerical values for the rare earths Gd and Ho are calculated.
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