Unravelling the Secret of Sulfur Confinement and High Sulfur Utilization in Hybrid Sulfur‐Carbons
Thermal condensation of inverse vulcanized sulfur‐carbon hybrids enables a bottom‐up sulfur confinement strategy, in which a protective carbon phase is progressively constructed around sulfur species. The resulting carbon nanodomains covalently tether sulfur chains and stabilize radical intermediates. This integrated architecture effectively suppresses
Tim Horner +9 more
wiley +1 more source
Adsorption and Sensing Behavior of Pristine, P-Doped, and Al-Doped Boron Nitride Nanosheets Toward Toxic Hydrogen Fluoride Gas: Insights from Density Functional Theory Analysis. [PDF]
Siddique N +6 more
europepmc +1 more source
The new Cu‐containing MOF (Me2NH2)(CuICl2)@[Cu4(INA)4Cl2O]·1.5dmf (3) contains a cation and an anion as guests and shows UV‐near‐mid‐IR absorption and near‐IR emission. MOF 3 shows gas‐solid reactivity in the presence of NH3 and HCOOH to yield two new 3D MOF.
Rajat Saha +10 more
wiley +1 more source
Mechanistic Insights Into Supercapacitive Swing Adsorption via Acid-Base Titrations. [PDF]
Khan FU, Landskron K.
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Ordered three‐dimensional anodic aluminum oxide (3D‐AAO) nanoarchitectures with longitudinal and transverse pores enable architecture‐driven metamaterials. The review maps fabrication advances, including hybrid pulse anodization, and shows how 3D‐AAO templates tailor properties across magnetism, energy, catalysis, and sensing.
Marisol Martín‐González
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Abiotic CO<sub>2</sub> reduction promoted by carbonate and phyllosilicate minerals on the primitive seafloor. [PDF]
Zhong Y +19 more
europepmc +1 more source
In Situ Amine Formation to Modulate MOF‐Derived PdIn N‐Doped Carbon Catalysts
An amine‐assisted approach converts PdIn‐MOF into PdIn intermetallic nanoparticles embedded in N‐doped carbon. In situ‐generated amines trigger early Pd nucleation, producing smaller PdIn domains than direct pyrolysis. Amine sterics and basicity tune composition and particle size, while solvent and amine co‐determine textural features.
Gonzalo Egea +9 more
wiley +1 more source
Au anchoring on 3D hierarchically porous Ti<sub>3</sub>C<sub>2</sub>T <sub><i>x</i></sub> MXene aerogels for enhanced selectivity, response and kinetics in room-temperature trimethylamine sensing. [PDF]
Quan Y, Zhou R, Cheng Z, Qiu X, Jin L.
europepmc +1 more source
Polymorph‐Specific Electronic Transduction in WO3 during Molecular Sensing
Metal‐oxide polymorphs with similar surface chemistry can nevertheless exhibit distinct sensing properties. In γ‐ and ε‐WO3, analyte adsorption appears comparable; yet, only ε‐WO3 induces a pronounced lattice electronic perturbation that accommodates charge in sub‐conduction band minimum states.
Matteo D'Andria +6 more
wiley +1 more source
Mechanism and Modeling of Moisture-Dependent Dielectric Properties of Cement-Based Composites for Enhanced Ground Penetrating Radar Applications. [PDF]
Wang T, Zhang B, Gao Y, Wang X, Wang D.
europepmc +1 more source

