Results 111 to 120 of about 2,000,296 (378)

Deciphering the Origin of Higher Shell Coordination on Single Iron Catalysts for Resilient Modulating Persulfate Oxidation Into Singlet Oxygen Pathway

open access: yesAdvanced Functional Materials, Volume 35, Issue 12, March 18, 2025.
This study reveals that higher shell S coordination can effectively modulate the spin state of FeN4 site via long‐range electronic interactions, giving rise to the oriented generation of singlet oxygen from peroxymonosulfate activation. Abstract Precise manipulation of coordination structure of single‐atom sites and establishment of schematic ...
Liang Zhang   +8 more
wiley   +1 more source

Polymer adsorption onto random planar surfaces: Interplay of polymer and surface correlation

open access: yes, 2005
We study the adsorption of homogeneous or heterogeneous polymers onto heterogeneous planar surfaces with exponentially decaying site-site correlations, using a variational reference system approach.
Alexey Polotsky   +3 more
core   +1 more source

Thermally Induced Gelling Systems Based on Patchy Polymeric Micelles

open access: yesAdvanced Functional Materials, Volume 35, Issue 12, March 18, 2025.
A novel strategy to design thermally induced gelling systems with tunable material properties is reported. Polymeric mixed‐shell micelles displaying multiple thermosensitive patchy domains formed hydrogels by assembling into well‐entangled worm‐like network structures upon heating to body temperature. The patchy micelle design significantly affects the
Binru Han   +9 more
wiley   +1 more source

Off‐Stoichiometry Engineering of the Electrical and Optical Properties of SrNbO3 Using Oxide Molecular Beam Epitaxy

open access: yesAdvanced Functional Materials, EarlyView.
The plasma edge of transparent conducting oxide SrNbO3 shifts from ∼2 eV in the visible range to 1.37 eV in the near‐infrared region by off‐stoichiometry using the vacancy sites as quasi‐substitutional virtual elements. This work advances the stoichiometry engineering of perovskite oxides using oxide molecular beam epitaxy, allowing synthesis beyond ...
Jasnamol Palakkal   +11 more
wiley   +1 more source

Solvent-free thermoplastic foaming for superelastic graphene monoliths

open access: yesNature Communications
Graphene monoliths with high porosity inherit extraordinary properties of graphene and establish a versatile platform to integrate diverse materials for multifunctional applications. To date, many methods have been invented to prepare graphene monoliths,
Zeshen Li   +9 more
doaj   +1 more source

Photoswitchable Conductive Metal–Organic Frameworks

open access: yesAdvanced Functional Materials, EarlyView.
A conductive material where the conductivity can be modulated remotely by irradiation with light is presented. It is based on films of conductive metal–organic framework type Cu3(HHTP)2 with embedded photochromic molecules such as azobenzene, diarylethene, spiropyran, and hexaarylbiimidazole in the pores.
Yidong Liu   +5 more
wiley   +1 more source

Taylor Dispersion with Adsorption and Desorption

open access: yes, 2012
We use a stochastic approach to show how Taylor dispersion is affected by kinetic processes of adsorption and desorption onto surfaces. A general theory is developed, from which we derive explicitly the dispersion coefficients of canonical examples like ...
Bénichou, Olivier   +3 more
core   +3 more sources

Ideal Molecular Sieving with a Dense MOF for Helium Upgrading with Highly Diffusion Selective Mixed Matrix Membranes

open access: yesAdvanced Functional Materials, EarlyView.
The separation of Helium gas from natural gas is challenging but highly important. MIL‐116(Ga), a “non‐porous” metal–organic framework is used as a molecular sieve to separate He from CH4. Druse‐like MIL‐116(Ga) particles are integrated into polysulfone mixed matrix membranes.
Ayisha Komal   +10 more
wiley   +1 more source

Unveiling Unidirectional Transport within Janus Membranes

open access: yesSmall Structures
Janus membranes with unidirectional transport capacity have shown broad potential across various fields of mass–energy transmission and conversion. However, the underlying mechanisms driving this transport remain unclear.
Kai Li   +5 more
doaj   +1 more source

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