Results 211 to 220 of about 965,539 (327)

Structural Exploration of Zirconium Metal–Organic Frameworks Through Linker Desymmetrization and Modulator Compensation

Advanced Materials, EarlyView.
A linker‐desymmetrization‐modulator‐compensation (LDMC) strategy for constructing structurally diverse Zr‐MOFs is reported. This approach reduces linker symmetry to create defects in Zr‐clusters, which can be compensated for by modulator coordination. Using this approach, we synthesized PCN‐1005 and PCN‐1006, featuring unprecedented Zr‐clusters. In PCN‐
Rong‐Ran Liang, Kun‐Yu Wang, Zongsu Han, Kui Tan, Yihao Yang, Zhaoyi Liu, Joshua Rushlow, Jiatong Huo, Hong‐Cai Zhou   +8 more
wiley   +1 more source

Management of caffeine in wastewater using MOF and perovskite materials: optimization, kinetics, and adsorption isotherm modelling. [PDF]

J Environ Health Sci Eng
Essam A, Eldek SI, Shehata N.
europepmc   +1 more source

COFs on MOFs: Layer‐by‐Layer Synthesis of MOF@COF Nanoparticles with Synergistic Adsorption

Advanced Materials, EarlyView.
A layer‐by‐layer strategy enables the growth of crystalline covalent organic framework (COF) shells on metal–organic framework nanoparticles, creating core–shell structures with tunable porosity. Ordered interstitial mesopores are formed during shell growth, which are connected with the COF's intrinsic micropores, thereby enhancing water sorption. This
Ana Guillem‐Navajas, Lucía Torrico‐García‐Viso, Jose Antonio Suárez del Pino, Nekane Aramburu‐Merino, Pilar Segovia, Enrique G. Michel, Josep Puigmartí‐Luis, Enrique Velasco, Pedro Tarazona, Daniel Maspoch, David Rodríguez‐San‐Miguel, Félix Zamora   +11 more
wiley   +1 more source

An Investigation into the Stability Source of Collagen Fiber Modified Using Cr(III): An Adsorption Isotherm Study. [PDF]

Molecules
Li J, Long W, Peng L, Guo L, Zhang W.
europepmc   +1 more source

Porous Iridium Oxide Inverse Opal Catalysts Enable Efficient PEM Water Electrolysis

Advanced Materials, EarlyView.
Porous iridium‐based inverse opal (IrOx‐IO) structures are introduced as high‐performance, unsupported PEM‐WE anode catalysts. Their electrochemical behavior is analyzed through porosity/surface area tuning, voltage breakdown, and circuit modeling.
Sebastian Möhle, Kerolus Nasser Nagi Nasralla, Jakub Drnec, William Chèvremont, Peter Strasser   +4 more
wiley   +1 more source

In Situ Amine Formation to Modulate MOF‐Derived PdIn N‐Doped Carbon Catalysts

Advanced Materials, EarlyView.
An amine‐assisted approach converts PdIn‐MOF into PdIn intermetallic nanoparticles embedded in N‐doped carbon. In situ‐generated amines trigger early Pd nucleation, producing smaller PdIn domains than direct pyrolysis. Amine sterics and basicity tune composition and particle size, while solvent and amine co‐determine textural features.
Gonzalo Egea, Jordan Santiago Martinez, M. Asunción Molina, Jaime Mazarío, Lucy Costley‐Wood, Christian Cerezo‐Navarrete, Carlo Marini, Eduardo Villalobos‐Portillo, Andrew M. Beale, Pascual Oña‐Burgos   +9 more
wiley   +1 more source

Hydrogel Thermostat Inspired by Photoprotective Foliage Using Latent and Radiative Heat Control

Advanced Materials, EarlyView.
Guided by Populus alba foliage, this hydrogel latent‐radiative thermostat (LRT) actively balances latent and radiative heat fluxes. An LRT switches solar reflectance, maintains high mid‐IR emissivity, and reversibly evaporates/regenerates water, while titanium oxide (TiO2) nanoparticles toughen the film.
Se‐Yeon Heo, Hyung Rae Kim, Yoonsoo Shin, Hyun Su Lee, Hyunkyu Kwak, Do Hyeon Kim, Dong Hyun Seo, Joo Hwan Ko, Hyo Eun Jeong, Sehui Chang, Min Seok Kim, Longnan Li, Jyotirmoy Mandal, Wei Li, Dae‐Hyeong Kim, Young Min Song   +15 more
wiley   +1 more source

An explicit multicomponent adsorption isotherm model: accounting for the size-effect for components with Langmuir adsorption behavior

Adsorption, 2018
Tom R. C. Van Assche, G. Baron, J. Denayer   +2 more
semanticscholar   +1 more source

Decoupling Dynamics and Crosslink Stability in Supramolecular Hydrogels Using Associative Exchange

Advanced Materials, EarlyView.
How does reorganization impact the stability of supramolecular hydrogels? In contrast to dissociative crosslink exchange, implementing associative exchange in macroscale DNA hydrogels enables decoupling of reorganization dynamics from thermal and mechanical stability.
Pierre Le Bourdonnec, Charafeddine Ferkous, Léo Comunale, Luca Cipelletti, Rémi Merindol   +4 more
wiley   +1 more source

Colloid‐Mediated Synthesis of Hierarchically Porous Amorphous Catalyst for Durable Industrial‐Scale Water Electrolysis

Advanced Materials, EarlyView.
A colloid‐mediated electroless plating (CMEP) strategy is proposed to fabricate hierarchically porous, amorphous Fe‐doped NiWB electrocatalysts under ambient conditions. The in situ formation of Fe‐W‐O colloidal species guides the formation of robust, porous catalyst layers with excellent mass transfer and durability, sustaining 500 mA cm−2 for 2000 h,
Yu Liao, Lei Li, Jingxian Zhang, Yangyang Chen, Sha Luo, Yan Qing, Cuihua Tian, Guanjie He, Yiqiang Wu   +8 more
wiley   +1 more source