Results 111 to 120 of about 560 (248)

In Situ Evolution of Artificial Interphase Enabling Stable, High‐Performance Lithium Metal Batteries

open access: yesAdvanced Energy Materials, EarlyView.
An evolutionary artificial interphase is presented for stable lithium metal batteries. A Mg3N2‐based layer spontaneously evolves into a hybrid interphase enriched with superionic Li3N and lithiophilic Mg‐Li alloy during cycling. This dynamic, self‐reinforcing mechanism effectively suppresses dendrite growth and enables exceptional long‐term cycling ...
Sangcheol Lee   +4 more
wiley   +1 more source

High‐Performance Elastomeric Lithium Metal Anodes Enabled by a Lithiophilic Monolayer‐Assembled Nano‐Crumpled Micro‐Concave Architecture

open access: yesAdvanced Energy Materials, EarlyView.
We report an elastomeric lithium metal anode integrating hierarchical nano–micro architectures with uniformly assembled lithiophilic amine functionalities. This design enables synergistic stress and interfacial regulation, effectively suppresses dendritic growth, and ensures stable cycling, highlighting elastomeric anodes as a promising platform for ...
Sungha Choi   +16 more
wiley   +1 more source

Palladium‐Doping‐Enabled Interface Synergy for Superb Ampere Level Ammonia Electrosynthesis From Nitrate

open access: yesAngewandte Chemie, EarlyView.
Isolated Pd sites in a metallic Co matrix boost nitrate‐to‐ammonia conversion. Pd doping optimizes intermediate adsorption and reconstructs the interfacial microenvironment, promoting cation enrichment and a hydrogen‐down‐oriented water network. This dual modulation facilitates proton transfer and intermediate stabilization, enabling high ammonia ...
Qun He   +6 more
wiley   +2 more sources

Tuning Interfacial Water Dynamics via Gd‐Doped Cu2O for High‐Rate Selective CO2‐to‐Ethanol Conversion

open access: yesAdvanced Energy Materials, EarlyView.
A Gd‐doped Cu2O electrocatalyst disrupts rigid interfacial hydrogen‐bonding networks, creating a free‐water‐rich microenvironment. This accelerates proton‐coupled electron transfer, enabling selective high‐rate CO2‐to‐ethanol conversion with 48.5% Faradaic efficiency at industrially relevant current densities.
Hyunwoo Kim   +11 more
wiley   +1 more source

Wrinkled Strain‐Enriched High‐Entropy Metallene Enables Cross‐Site Tandem Nitrate‐to‐Ammonia

open access: yesAngewandte Chemie, EarlyView.
A wrinkled 2D PdFeCoNiCuIn high‐entropy metallene overcomes the low atom utilization of high‐entropy alloys. Indium‐induced strain and p‐d hybridization enable a cross‐site tandem pathway for nitrate reduction to ammonia. It achieves 99.3% Faradaic efficiency and an NH3 yield rate of 4.55 mmol h−1 mgcat−1.
Tianfang Yang   +6 more
wiley   +2 more sources

Complex Iridium Oxides Converge In Structure And Reactivity During Acidic Oxygen Evolution Electrocatalysis

open access: yesAdvanced Energy Materials, EarlyView.
Ir‐based double perovskites restructure during acidic oxygen evolution electrocatalysis through dissolution of non‐Ir cations and convergence toward IrOx active‐site motifs with similar structure and intrinsic activity across compositions. The identity of the dissolving cations controls dissolution and surface reconstruction kinetics, clarifying how ...
Harrison H. Lippie   +5 more
wiley   +1 more source

Tunnel‐Framework Interphase Driving Rapid Zn2+ Diffusion for Long‐Life Zn Metal Anodes

open access: yesAdvanced Energy Materials, EarlyView.
The construction of an artificial interphase with 3D tunnel‐framework effectively suppresses interfacial water‐induced side reactions and dendrite growth. ABSTRACT Aqueous zinc‐ion batteries (AZIBs) are presently attracting considerable interest for large‐scale energy storage owing to their low cost and high safety.
Kunpeng Gao   +3 more
wiley   +1 more source

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