Results 231 to 240 of about 2,467 (304)

Wrinkled Strain‐Enriched High‐Entropy Metallene Enables Cross‐Site Tandem Nitrate‐to‐Ammonia

open access: yesAngewandte Chemie, EarlyView.
A wrinkled 2D PdFeCoNiCuIn high‐entropy metallene overcomes the low atom utilization of high‐entropy alloys. Indium‐induced strain and p‐d hybridization enable a cross‐site tandem pathway for nitrate reduction to ammonia. It achieves 99.3% Faradaic efficiency and an NH3 yield rate of 4.55 mmol h−1 mgcat−1.
Tianfang Yang   +6 more
wiley   +1 more source

Ordered Pt3Mn Intermetallic Nanoparticles Supported on Atomically Dispersed Mn–N–C as Electrocatalysts for Fuel Cells

open access: yesAngewandte Chemie, EarlyView.
Ordered L12‐Pt3Mn intermetallic alloys are uniformly deposited onto atomically dispersed Mn–N–C supports. The synergistic effect between MnN4 sites and Pt3Mn elevates interfacial binding strength and dissolution barriers while favorably weakening *OH adsorption. It delivers exceptional catalytic activity and stability in fuel cells, serving as an ideal
Gongjin Chen   +8 more
wiley   +1 more source

Matching the Coupling of Valence Electrons in the Oxide Interface to Perturb the Magnetic Order Enhancing Oxygen Reduction in Zinc–Air Batteries

open access: yesAngewandte Chemie, EarlyView.
Sub‐5 nm Fe2O3/Sm2O3 heterojunction nanoparticles are anchored on nitrogen‐doped carbon nanofibers, featuring coupled Fe(3d)‐O(2p)‐Sm(4f) orbitals at the interface. The resulting super‐exchange induces antiparallel magnetic ordering at heterointerfaces, suppressing spin‐dependent interaction between surface OH* species and Fe sites to facilitate OH ...
Jing Li   +9 more
wiley   +1 more source

A Decoupled Cycling Architecture of Asymmetric Zinc‐Air Battery Unlocks Stable Catalyst Strategy and pH‐Dynamic Influence

open access: yesAngewandte Chemie, EarlyView.
A decoupled cycling architecture along with cost‐effective membrane and efficient catalyst is developed for asymmetric zinc‐air battery. The decoupled design ensures stable operation of catalyst and the pH‐dynamic influence on battery performance is explored, which provides paths for efficient utilization of pH‐decoupling electrolytes.
Yeshu Tan   +6 more
wiley   +1 more source

Data‐ and Theory‐Guided Design of Dual‐Role V‐Doped RuO2 for High‐Performance Acidic Oxygen Evolution

open access: yesAngewandte Chemie, EarlyView.
A data‐ and theory‐guided paradigm, leveraging large‐scale data mining of 718 catalysts and microkinetic modeling, identifies V‐doped RuO2 as optimal for acidic OER. Vanadium doping drives electron withdrawal from Ru centers, generating Lewis acidic sites that polarize O–H bonds and accelerate deprotonation kinetics. Experimental validation achieves an
Zhongliang Liu   +10 more
wiley   +1 more source

Innovative Biosensor Platforms for the Detection of Metformin in Diabetes Management. [PDF]

open access: yesInt J Anal Chem
Jafarzadeh S   +6 more
europepmc   +1 more source

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