Results 221 to 230 of about 132,769 (300)

Covalent Insertion of a Mn(Salen) Type Complex in Cross‐Linked Protein Crystals: Design of an Enantioselective Artificial Epoxidase

open access: yesChemistry – A European Journal, EarlyView.
An Artificial metalloenzyme was designed by a Michael addition between a MnSalen complex and a cysteine residue within NikA crystals. The heterogeneous catalyst was found capable of an enantioselective and stereospecific epoxidation of cis‐β‐methylstyrene in cristallo.
Manel Boukhallat   +8 more
wiley   +1 more source

Usefulness of a cuffless blood pressure monitoring wearable device for aerobic exercise to estimate anaerobic threshold in healthy adults. [PDF]

open access: yesFront Physiol
Katsumata T   +9 more
europepmc   +1 more source

A New Spin on Photocatalysis: Vortex Fluidic‐Driven Photooxidations Enabled by Solution‐Processable Microporous Polymers

open access: yesChemistry – A European Journal, EarlyView.
Newly developed polymers with intrinsic microporosity (PIMs) were combined with benzo[c][1,2,5]thiadiazole (BTZ) to be used as visible light photocatalytic coatings on the Vortex Fluidic Device (VFD). The VFD's rapid rotation and continuous flow capabilities enhanced singlet oxygen and superoxide radical reactions, achieving a dramatic eightfold ...
Leonardo Amicosante   +9 more
wiley   +1 more source

Nitrooxylation in Organic Synthesis: From Classical Nitrate Ester Formation to Modern Catalytic Strategies

open access: yesChemistry – A European Journal, EarlyView.
Nitrooxylation—the installation of nitrate esters (–ONO2) has evolved from classical mixed‐acid protocols to catalytic and mechano‐, flow‐, photo‐, and electrochemical strategies. This review delineates ionic and radical manifolds for C–ONO2 bond formation, emphasizing mechanistic control, selected substrate scope, and selectivity.
Jayanta Dey, Dmitry Katayev
wiley   +1 more source

The effect of aerobic exercise with blood flow restriction on substrate utilization and energy expenditure. [PDF]

open access: yesFront Sports Act Living
Lauver JD   +6 more
europepmc   +1 more source

Cyclopropylamine‐Derived Distonic Iminium Radicals: Photoinduced Strategies in Chemo‐ and Stereo‐Selective Synthesis

open access: yesChemistry – A European Journal, EarlyView.
Cyclopropylamines have emerged as powerful photocatalytic building blocks. Upon light‐induced single‐electron oxidation, they undergo strain‐release ring opening to generate distonic iminium radicals that enable diverse transformations, including ring‐opening functionalization, formal [3 + 2] cycloadditions, radical cascades, and asymmetric bond ...
Maria Chiara Cabua   +3 more
wiley   +1 more source

Economic and environmental implications of the development of UASB reactors in Mexico for sustainable industrial wastewater treatment

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract The objective of this work is to demonstrate that the inclusion of an up‐flow anaerobic sludge bed (UASB reactor) within an industrial wastewater treatment plant reduces the plant's investment and operating costs compared to a system based solely on conventional complete‐mix activated sludge (CMAS), operating under the same design principles ...
Juan Manuel Morgan‐Sagastume   +1 more
wiley   +1 more source

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