Results 191 to 200 of about 4,121,610 (230)

Spin‐Polarized Interfaces Redirect CO2 Reduction From CO to Formate

open access: yesAngewandte Chemie, EarlyView.
The chiral electrocatalyst exploits the CISS effect to establish a spin‐polarized interface that selectively promotes formate production during CO2 reduction while effectively suppressing the competing hydrogen evolution. ABSTRACT Achieving high product selectivity in electrocatalytic carbon dioxide reduction (CO2RR) remains a critical challenge due to
Fan He   +4 more
wiley   +1 more source

Electron Bridge Enhanced Charge Polarization Enables Efficient and Ultra‐Long Stable Urea Electrosynthesis

open access: yesAngewandte Chemie, EarlyView.
An electron bridge strategy is developed to regulate charge polarization in Pd1 and Ni1 dual single‐atom sites, promoting CO2 reduction, nitrate reduction, and C–N coupling simultaneously. The resulting catalyst achieves efficient urea electrosynthesis with high activity and record durability over 1700 h.
Fan Wu   +11 more
wiley   +1 more source

Key Drivers of Activity and Selectivity in Cu‐Based Catalysts for Methanol Synthesis From CO2: Insights From Atomically Dispersed Promoters

open access: yesAngewandte Chemie, EarlyView.
Mechanistic studies on model Cu─M/SiO2 catalysts (M = Zn, Ga, and In) reveal that promoters enable a formate spillover pathway from Cu to Mn+ (n = 2 or 3) sites. The promoter's electronic effect on formate bond strengths serves as a quantitative descriptor for activity and selectivity, balancing spillover dynamics with intermediate stabilization to ...
Nat Phongprueksathat   +6 more
wiley   +1 more source

Electronically Driven Combustion of Energetic Ionic Liquids in a Microcell Reactor. [PDF]

open access: yesACS Omega
Hauck C   +5 more
europepmc   +1 more source

Modulating Local Coordination in Single‐Atom Catalysts: From Fundamental Concepts to Emerging Breakthroughs in Electrocatalysis

open access: yesAngewandte Chemie, EarlyView.
This review summarizes atomic‐level design strategies for single‐atom catalysts, emphasizing modulation of the local coordination environment, active‐site geometry, and metal‐support interactions to optimize catalytic activity and stability in electrocatalytic energy conversion applications.
Ashwani Kumar, Harun Tüysüz
wiley   +1 more source

Microbial Diversity and Hydrocarbon-Oxidizing Bacteria in Coastal Waters and Sands Contaminated by the Fuel Oil Spill in the Black Sea. [PDF]

open access: yesMicroorganisms
Semenova EM   +7 more
europepmc   +1 more source

Boosting Charge Storage in Ferri/Ferrocyanide‐Based Alkaline Redox Flow Batteries

open access: yesAngewandte Chemie, EarlyView.
By modifying the solvation environment, cation engineering through Li+ substitution of traditional K+ or Na+ boosts the alkaline solubility of the ferri/ferrocyanide catholyte redox couple, providing a viable pathway to overcome the long‐standing challenge of energy density limitations for aqueous redox flow batteries (RBFs).
Mahla Sarfaraz Khabbaz   +6 more
wiley   +1 more source

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