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Diastereoselective Addition of Alcohol to Diastereotopic Silylenes
Journal of the American Chemical Society, 2003The successful example of diastereoselective addition of alcohol to diastereotopic silylenes is reported.
T. Sanji +3 more
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Free-radical addition of primary alcohols to unsaturated alcohols
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 19621. Reaction, initiated by t-butyl peroxide, between normal primary alcohols and unsaturated alcohols with the double bond in the allyl position leads to 1,4-alkanediols. 2. At molar proportions of saturated alcohol: allyl alcohol: peroxide of 20:1: 0.2–0.3, a reaction time of six hours, and a temperature of 160–170° the yields of 1∶1 ...
G. I. Nikishin, V. D. Vorob'ev
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Addition of alcohols to 4-methylene-1,3-dioxolanes
Журнал общей химии, 2023The addition of alcohols to 2-methylene-1,4-dioxaspiro[4.5]decane under the conditions of CF3CO2H catalysis occurs with the selective formation of the corresponding alkoxy derivatives. The conditions that ensure the preparative isolation of target compounds in 63-94% yields are determined, and the relative activity of alcohols in the addition reaction ...
S. A. Sokov +4 more
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Alcohol and cancer: benefits in addition to risks?
The Lancet Oncology, 2005No ...
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Platinum(II)‐Catalyzed Addition of Alcohols to Alkynes.
ChemInform, 2004AbstractFor Abstract see ChemInform Abstract in Full Text.
John W. Hartman, Luke Sperry
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Addition of alcoholes to asymmetric epoxides
Polymer Bulletin, 1980Formation of some asymmetric glycoles by the addition of some alcoholes or glycoles to the asymmetric epoxides in the presence of HC104 were investigated by 13C NMR and the results were simply discussed. It was cleared that the formation of the adducts were led by the electronegativity of the side groups as well as steric nature of the nucleophile ...
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