Characterization of prepared soft-shelled turtle dishes of different pretreatment combined with irradiation based on flavor profiles using <i>E</i>-nose, <i>E</i>-tongue and HS-SPME-GC-MS. [PDF]
Xu Y+15 more
europepmc +1 more source
Mannich Reaction of Secondary Benzylzinc Reagents: Synthesis of α,β‐Disubstituted β‐Arylethylamines
The organometallic Mannich multicomponent reaction (MCR) of secondary benzylzinc reagents is described. The final α,β‐disubstituted β‐arylethylamines are obtained in generally high yields. The reaction is however characterized by a general lack of diastereoselectivity. A possible explanation is provided.
Baptiste Leroux+6 more
wiley +1 more source
Direct carbonyl reductive functionalizations by diphenylphosphine oxide. [PDF]
Liu F+9 more
europepmc +1 more source
An indolizidine alkaloid, (‐)‐8a‐epi‐lentiginosine was synthesized from d‐glucose using the Pd‐BiPhePhos catalyzed intramolecular Tsuji‐Trost reaction of non‐derivatized allylic alcohol as a key construction of the hydroxylated pyrrolidine ring to give the desired product in good yield and high diasterespecificity stereospecificity (dr = 97:3).
Sunisa Akkarasamiyo+3 more
wiley +1 more source
Photoredox/Cr-catalyzed enantioselective radical-polar crossover transformation via C-H functionalization. [PDF]
Tang SY+4 more
europepmc +1 more source
meso‐Free porphyrinoids are recognized as a versatile platform for further functionalization and oligomerization. The synthesis and characteristic features of such meso‐free porphyrinoids are reviewed. Abstract meso‐Unsubstituted (meso‐free) porphyrins have been an effective platform for creating versatile peripherally functionalized porphyrins and ...
Takayuki Tanaka+2 more
wiley +1 more source
Impact of Oil Temperature and Splashing Frequency on Chili Oil Flavor: Volatilomics and Lipidomics. [PDF]
Li X+7 more
europepmc +1 more source
Thiophene Containing Polycyclic Aromatic Hydrocarbon Monkey Saddles
Negatively curved chiral polycyclic aromatic hydrocarbons (PAHs) gained a lot of interest in research over the past years. By replacing phenyl against thiophene units in a monkey saddle shaped PAH, it was possible to further tune the photophysical and electrochemical properties as well as influence the racemization barrier of these three‐dimensional ...
Tobias Kirschbaum+6 more
wiley +1 more source
Stereo- and Enantioselective Syntheses of (Z)-1,3-Butadienyl-2-carbinols via Brønsted Acid Catalysis. [PDF]
Chen M.
europepmc +1 more source
Sugar‐sensing swodkoreceptors and swodkocrine signaling
Sugar‐sensing swodkoreceptors that trigger swodkocrine signaling. Abstract Sugars are one of the major metabolites and are essential for nucleic acid synthesis and energy production. In addition, sugars can act as signaling molecules. To study sugar signaling at the systemic level, there is an urgent need to systematically identify sugar‐sensing ...
Savani Anbalagan
wiley +1 more source