Results 41 to 50 of about 31,828 (258)

Electrochemically Driven Regioselective Radical Functionalization of Allenes: Scope and Mechanistic Insights

open access: yesAdvanced Science, EarlyView.
Allenes emerge as powerful platforms for electrochemical functionalization through radical pathways. Selective radical addition at the central carbon triggers anodic oxidation and intramolecular cyclization, enabling efficient synthesis of oxazolines and oxazolidine‐2‐imines without external oxidants.
Pranjal Pyne   +5 more
wiley   +1 more source

Treating vitamin D deficiency in children with type I diabetes could improve their glycaemic control

open access: yesBMC Research Notes, 2017
Background and aims The relationship between vitamin D deficiency and type I DM is an ongoing area of interest. The study aims to identify the prevalence of vitamin D deficiency in children and adolescents with T1DM and to assess the impact of treatment ...
Dinesh Giri   +6 more
doaj   +1 more source

Rapid Photogelation of Low‐Concentration Polymer Solutions via Photodimerization of o‐Ethylnitrobenzene

open access: yesAdvanced Science, EarlyView.
Upon UV irradiation, flexible and tough hydrogels are formed rapidly (>0.5 s) from dilute (>0.5 wt%) solutions of o‐ethylnitrobenzene–modified PVA. At ∼1.5 wt%, the hydrogels withstand up to 10 MPa compression, remain handleable even after 200‐fold swelling.
Masaaki Okihara   +4 more
wiley   +1 more source

Dynamic Electronic Tracking and Escalation to reduce Critical care Transfers (DETECT): the protocol for a stepped wedge mixed method study to explore the clinical effectiveness, clinical utility and cost-effectiveness of an electronic physiological surveillance system for use in children

open access: yesBMC Pediatrics, 2019
Background Active monitoring of hospitalised adults, using handheld electronic physiological surveillance systems, is associated with reduced in-patient mortality in the UK.
Gerri Sefton   +9 more
doaj   +1 more source

Disinfection Efficiency Among Black Alder and Hybrid Alder Genotypes and Their Influence on Alder Seed Germination In Vitro

open access: yesEnvironmental Microbiology Reports
ABSTRACT The presented study aimed to test a set of Alnus genotypes, including hybrids of black and grey alders ( A. glutinosa  ×  A. incana
Vytautas Čėsna   +3 more
openaire   +2 more sources

Site‐Specific Protein Bioconjugation Through Cellular Incorporation of Noncanonical Amino Acids

open access: yesAngewandte Chemie, EarlyView.
Genetic code expansion (GCE) enables site‐specific installation of noncanonical amino acids containing bioorthogonal conjugation handles, allowing precise, homogeneous protein modification. This review examines the principles of orthogonal translation, surveys the chemistries available for chemoselective labeling, and highlights emerging multi‐site ...
Rahul Sarkar   +2 more
wiley   +2 more sources

Potential for monetisation and utilisation of wood raw material from pioneer tree species stands in the Czech Republic

open access: yesJournal of Forest Science
Pioneer tree species in the Czech Republic include birch, alder and aspen. From an economic point of view, birch seems to be the most promising. Greater use of timber from pioneer tree species in higher value-added products is currently limited by the ...
Roman Dudík   +4 more
doaj   +1 more source

Supramolecular Degraders: An Emerging Paradigm in Targeted Protein Degradation

open access: yesAdvanced Science, EarlyView.
Dynamic supramolecular assembly reshapes targeted protein degradation by coordinating modular degrader construction, delivery, functional integration, and intracellular assembly or activation across proteasomal, endosomal–lysosomal, and autophagy–lysosomal pathways.
Kongjun Liu   +8 more
wiley   +1 more source

Cobalt‐Catalyzed C─N Bond Formation via Metal‐Hydride Hydrogen Atom Transfer (MHAT)

open access: yesAngewandte Chemie, EarlyView.
Cobalt‐catalyzed metal‐hydride hydrogen atom transfer (Co‐MHAT) converts simple alkenes into C─N bonds under mild, near‐neutral conditions. A shared Co─H‐initiated radical/organocobalt intermediate is channeled into radical trapping, radical‐polar crossover, or radical ligand transfer, unifying hydroamination, hydroazidation, hydroamidation, and remote
Arman Khosravi, Ming‐Yu Ngai
wiley   +2 more sources

Slope stability analysis considering weight of trees and root reinforcement

open access: yesJournal of Environmental Engineering and Landscape Management, 2019
We study the effect of roots of alder trees on soil reinforcement and slope stabilization. Two types of soil, i.e. Marl and Clayey soils and alders of three ages are considered.
Majid Lotfalian   +3 more
doaj   +1 more source

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