Results 181 to 190 of about 369,121 (287)

Double Reduction of Ph3B to a Dianionic Borane With a Powerful SrI Intermediate

Angewandte Chemie, EarlyView.
Although dianionic boranes follow the octet rule and are isoelectronic to carbanions or amines, the high electron density combined with the electropositive nature of the B center make them highly unstable species. In this study, we present synthesis and full characterization of a complex in which Ph3B2− is sandwiched between two Sr2+ ions and describe ...
Michael Morasch, Marcel A. Schmidt, Tanuja Tewari, Jens Langer, Sjoerd Harder   +4 more
wiley   +2 more sources

An Accelerated Concrete Prism Test for Evaluating Fly Ash Mitigation of Alkali-Silica Reaction in Reactive Tuff Aggregates. [PDF]

Materials (Basel)
Liu X, Zhang Y, Lv G, Li W, Huang X, Deng M.   +5 more
europepmc   +1 more source

An Alkali Amide Approach to Triphosphabenzenes

Angewandte Chemie, EarlyView.
Alkali metal amides offer a simple route to phosphorus aromatics. LiNMe2 catalyzes [2+2+2] cyclotrimerization of a phosphaalkyne, while tetrahydrofuran (THF) stabilizes a λ4‐triphosphabenzene anion intermediate. Using KN(SiMe3)2 switches reactivity to arene C(sp3)─H activation, giving benzylated λ4‐triphosphabenzenes and rare λ5‐triphosphabenzenes ...
Owen J. Jones, Andrew D. Bond, Ruth L. Webster   +2 more
wiley   +2 more sources

Concise and Modular Access to a Chiral Biaryl Monophosphine Library and Downstream Use in Catalytic Enantioselective Transformations

Angewandte Chemie, EarlyView.
A unified three‐step strategy for a high‐diversity chiral air‐stable biaryl monophosphine library is presented. An atroposelective CpxIrIII‐catalyzed C─H arylation followed by phosphine oxide reduction provides the biaryl ligand building blocks with three different diversity points.
Vitalii Smal, Anastasiia Vorobei, Nicolai Cramer   +2 more
wiley   +2 more sources

Identification of Candidate Genes for Alkaline Tolerance in Rice Seedlings Using BSA-Seq and RNA-Seq. [PDF]

Genes (Basel)
Ma B, Du H, Wang X, Liu X, Sheng X, Tan K, Hu J, Liu K, Liu R, Ma Y, Guo X.   +10 more
europepmc   +1 more source

Tailoring plant-based food emulsions with oil bodies and proteins recovered by alkali aqueous extraction from rapeseed (<i>Brassica napus</i> L.) oilseeds. [PDF]

Curr Res Food Sci
Rabesona H, Lopez C.
europepmc   +1 more source

Structural Evolution and Oxygen Evolution Performance of NiFe‐Based Electrocatalysts in Phosphate‐Containing Electrolytes at Non‐Extreme pH

Angewandte Chemie, EarlyView.
Phosphate acts as a selective interfacial probe of nickel–iron oxide oxygen evolution electrocatalysts at non‐extreme pH. It reversibly suppresses Ni‐centered oxidation and activity, whereas cycling through the Ni reduction region promotes irreversible catalyst loss.
Hiroki Komiya, Keisuke Obata, Joonbaek Jang, Samuele Lasagna, Sotiris Tsatsos, Lichen Bai, Andrea Martini, Timon Wagner, Janis Timoshenko, Arno Bergmann, Beatriz Roldan Cuenya, Kazuhiro Takanabe   +11 more
wiley   +2 more sources

A super-bulky phosphanide ligand enables the observation of scalar coupling between ³¹P and ⁷Li, ²³Na, ⁸⁵Rb/⁸⁷Rb, and ¹³³Cs.

Dalton Trans
Hadadi A, Wills CY, Dixon CM, Waddell PG, Izod K.   +4 more
europepmc   +1 more source

Enhancing CO₂ Mineralization and Mechanical Performance of Fly Ash-Based Alkali-Activated Mortar Using Calcined Seashell Ash. [PDF]

Materials (Basel)
Intarabut D, Sukontasukkul P, Sinyoung S, Sappakittipakorn M, Phoo-Ngernkham T, Sae-Long W, Puttiwongrak A, Limkatanyu S.   +7 more
europepmc   +1 more source

Interfacial Water‐Networks Regulate the Anodic Stability of Carbon Electrodes

Angewandte Chemie, EarlyView.
The hydrogen‐bonding networks of interfacial water serve as active stability descriptors for carbon anodes: disrupted water‐networks accelerate anodic carbon corrosion, whereas strongly hydrogen‐bonded networks suppress it. This principle enables extension of the stable potential window of carbon electrodes through ionomer‐defined interfaces, as ...
Junsic Cho, David Hernández‐Castillo, Jinjong Kim, Tomohiko Utsunomiya, Haesol Kim, Taejung Lim, Young Yong Kim, Hyo Sang Jeon, Hyung‐Suk Oh, Yu Katayama, Sang Hoon Joo, Kai S. Exner, Chang Hyuck Choi   +12 more
wiley   +2 more sources