Results 211 to 220 of about 8,486 (282)

Luminescence Vapochromism of a Cu(I)/Na Phosphane Iodide Assembly Based on a Secondary‐Sphere Sodium Response

open access: yesAngewandte Chemie, EarlyView.
The luminescence of a heterometallic d‐s {Cu2I2Na2} phosphane‐phosphinate aggregate is regulated by an interplay of Na+–π/I– contacts and reversible coordination of oxygen‐containing organic molecules to Na ions. Structural variations caused by the incoming guest lead to a wide and selective variation of the emission color and illustrate a new approach
Henna Korhonen   +10 more
wiley   +1 more source

Effects of Dual Inhibition of VEGF-A and Angpt-2 on Angiogenesis and Lymphangiogenesis in an Alkali-Induced Corneal Injury Model. [PDF]

open access: yesGenes Cells
Kuribayashi H   +13 more
europepmc   +1 more source

Reinforcing Particle Architectural Stability of Li‐Rich Cathode With Enhanced Anionic Redox Reaction Reversibility

open access: yesAngewandte Chemie, EarlyView.
In this work, we establish a direct correlation between internal compactness and particle architectural stability, identifying it as a key descriptor of cathode structural integrity. Simultaneously, the capacity contribution and compensation mechanism of ARR are resolved, revealing that the extent of irreversible capacity loss is governed by both the ...
Yizhen Huang   +24 more
wiley   +1 more source

Deprotonation and Alkylation of Weakly Acidic C(sp3)─H Bonds Through In Situ Generation of a Strong Hydride Base From 1,1,3,3‐Tetramethyldisiloxane and Potassium tert‐Butoxide

open access: yesAngewandte Chemie, EarlyView.
The use of 1,1,3,3‐tetramethyldisiloxane (TMDSO) and potassium tert‐butoxide enables direct alkylation of weakly acidic carbon–hydrogen bonds with alkyl halides. Experimental and computational studies support the formation of a substrate‐associated hydride‐like base, providing a single‐step alternative to the classical deprotonation and electrophile ...
Piers St. Onge   +4 more
wiley   +1 more source

Proteomic Analysis of Lactococcus lactis FM03 Under Prolonged Alkaline Stress. [PDF]

open access: yesEnviron Microbiol
Bendig TAL   +4 more
europepmc   +1 more source

Ionic Liquid Electrolytes for Extreme Temperature Conditions: Challenges and Perspective

open access: yesAngewandte Chemie, EarlyView.
Ionic liquids (ILs) have gained great attention as safe electrolyte components in recent years. This review elucidates the temperature effects on IL‐based electrolytes from molecular configurations, physicochemical properties, and interfacial chemistry, raises the challenges and design strategies operating at low‐ and HT, providing valuable guidance ...
En Xie   +11 more
wiley   +1 more source

Rerouting Oxygen Evolution Through Interfacial Carbonate Chemistry in Near‐Neutral Seawater Electrolysis

open access: yesAngewandte Chemie, EarlyView.
Carbonate species play a previously overlooked role in near‐neutral seawater electrocatalysis. By coupling electrochemical hydrodynamics with mesoscopic simulations, we reveal a plausible carbonate‐mediated route in which carbonate functions as an interfacial proton acceptor and water as the oxygen donor, showing a possible mechanistic picture of ...
Miao Wang   +2 more
wiley   +1 more source

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